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Electron Transfer Kinetics in Redox Flow Batteries

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Electron Transfer Kinetics in Redox Flow Batteries ( electron-transfer-kinetics-redox-flow-batteries )

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8 Half – cell performance of Carbon Felt Samples Many studies have investigated the performance of VRFB cells using charge / discharge cycling, with varying experimental parameters and efficiency results, (Table 8.1). Table 8.1: Non-exhaustive selection of full cell measurement conditions and efficiency results. Other important parameters not shown include operating temperature, whether the electrolyte is recirculated and the duration of the experiments. Ref [226] [226] [227] [227] [221] [221] [222] [222] [228] [228] 113 Elect. Thick . mm 6 6 Electrode Treatment 400°C Air 6 hrs None Are [V]/ S.O.C Flow a [H2SO4] cm2 M % mL min-1 Mem. N117 N117 N117 N117 N115 N115 SFPAE 28 um SFPAE 28 um AEM 56 um N212 51 um Elim i VE CE EE (V) mA % % % cm-2 4.6 None 4.6 None 0.3 1300°C 4:1 N2:CO2 1 hr 0.3 None 90 72.4 435 28.1 60 92.6 140 69 20 96 80 83 20 91 80 71 96.1 69.5 96.7 27.1 93 86 95 66 94 90 97.9 81 100 91 94 66.7 6 6 6 6 400°C Air 6 hrs 400°C Air 6 hrs 400°C Air 6 hrs 400°C Air 6 hrs 10 1/4 10 1/4 31 1.6/4 31 1.6/4 12 1.5/3 12 1.5/3 10 1.4/2 10 1.4/2 10 1/ 2.5 10 1/ 2.5 100/0 None 100/0 None 50/50 100 50/50 100 100/0 20 100/0 20 100/0 100 100/0 100 100/0 100 100/0 100 0.8 - 1.7 0.8 - 1.7 0.7 - 1.8 0.7 – 1.8 0.9 – 1.65 0.9 – 1.65 0.7-1.7 0.7-1.7 0.7 - 1.7 0.7 - 1.7 40 87.1 -- 40 60.3 --

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