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Chapter 2. Redox Flow Batteries 14 Table 2.1: Literature values of the quinone-based (top section) and ferri-/ferrocyanide-based (middle section) electrolytes presented in this chapter. Literature values of an additional quinone relevant for discussions in later chapters are also included (bottom section). (a) Full cell study; (b) symmetric cell study; (c) calculated based on experimental parameters stated in the reference; (d) with limited SOC; (e) buffered solution. Species Concentration [M] Solvent pH Redox potential Solubility [V] vs. SHE [M] Fade rate [%d−1] Reference 3M H2SO4 AQDS 1 1MH2SO4 0 0.904 NA NA 0.1–0.2 [23] [24, 27, 52] [29] [53] [24] [24] [24] [25] [25] BQDS 0.25 DHAQ DBEAQ 0.5 2M KOH 0.1 1.2MKOH 0.5 1.01 M KOH 0.1 1.2MKOH 0 0.213 >1.0 14 −0.684 >0.6 7.6(a,c) 14 −0.684 >0.6 5(b) / 0.14(a,d) 12 −0.515 0.6 0.04(a) 14 −0.515 1.1 <0.01(b) DPPEAQ [Fe(CN)6 ]3 – /4 – 0.65 2.3MKOH 0.5 NA 0.1 0.1 M KOH 14 −0.515 9 −0.39(e) 13 −0.47(e) 1.1 0.75 NA 0.007(b) 0.014(a) 0.02(b) [Fe(CN)6 ]3 – /4 – DHBQ 0.2 1 M NH4Cl 0.2 1M KOH 7.2 0.37 14 0.43 1.10 / 0.73 NA 0.6 0.2 [49] [47] 0.5 2M KOH 14 −0.72 4.31 12.5(c) [32]PDF Image | Organic Redox Flow Batteries 2023
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