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Figure 6.27: (a) Nyquist plots recorded on a full cell of 0.1 M DBEAQ adjusted to pH 12 with KOH against 0.15M K4[Fe(CN)6]+0.05M K3[Fe(CN)6] dissolved in 1.0M KCl adjusted to pH 12 with KOH. The impedance was recorded from 100 kHz to 100 mHz at a flow rate of 50 mL min−1, a cell temperature of 35 ◦C, and at SOC values ranging from 10 % to 100 %. (b) Semi-log Bode plots of the imaginary impedance. Figure 6.28: Illustration of the relation between the exchange current density (red line) and the charge transfer resistance (blue line) as functions of the concentration of oxidised and reduced redox species. Calculated using Equations 3.6 and 3.46 and values of T = 308.15 K, n = 1, k0 = 1 × 10−3 cm s−1, α = 0.5, and concentrations ranging from 1–200 × 10−6 mol cm−3. 6.2. Results and Discussion 113PDF Image | Organic Redox Flow Batteries 2023
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