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Redox Flow Batteries Vanadium to Earth Quinones

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Redox Flow Batteries Vanadium to Earth Quinones ( redox-flow-batteries-vanadium-earth-quinones )

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V/Ce (2002) V-polyhalide (2003) Zn/Ce (2004) Soluble Pb/PbO2 (2005) Zn/Ni (2007) Cu/PbO2 (2008) Zn/O2 (2009) Cd-choranil (2009) V/Fe (2011) V/O2 (2011) Li4Ti5O12/LiCoO2 (2011) Li4Ti5O12/LiNi0.5Mn1.5O4 (2011) Li-Ferricyanide (2011) Graphite/LiCoO2 (2011) Figure 2.4 – Latest progressions on new redox flow batteries. 2.6 Redox flow batteries configuration Redox flow batteries can be classified by active species or solvent (aqueous or non- aqueous respectively). Figure 2.5 shows a generic RFB system. In the discharge mode, an anolyte solution flows through a porous electrode and reacts to generate electrons, which are conducted through the external circuit. The charge-carrying species are then transported to a separator (ion exchange membrane (IEM) or nano-porous membrane), which separates the anolyte and catholyte solutions. Typically for the anode (negative electrode) and the cathode (positive electrode), respectively, the general reactions can be written as: The key transport mechanisms are shown in Figure 2.6 for this generic system. The dominant losses in these systems, other than charge transfer reaction kinetics, are related to the charge and mass transport in the electrolyte and separator, 23

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