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Redox Flow Batteries Vanadium to Earth Quinones

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Redox Flow Batteries Vanadium to Earth Quinones ( redox-flow-batteries-vanadium-earth-quinones )

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750 0 -750 -1500 -2250 V2+ V3+ + e- GF@TiO2-x:H GF-P GF@TiO2 0 -100 -200 -300 a) -400 -500 V3+ + e- -0.3 -0.2 V2+ GF-P GF@TiO2 I / mA g-1 I / mA g-1 GF@TiO2-x:H -0.9 0.0 0.3 0.6 -0.1 0.0 V3+ + e- V2+ 2H+ + 2e- H2 -0.6 -0.3 b) E vs. NHE / V E vs. NHE / V Figure 6.15. - a) cyclic voltammetry performed for negative half-cell using the as- prepared electrodes in 0.05 M V3+ and 1M H2SO4. Scan rate: 2 mV/s. b) Onset potential obtained from figure a). The origin of the improved electrochemical behaviour can be caused by an increment in electrical donor properties as a consequence of oxygen- vacancies generation in the lattice of the TiO2 after hydrogen treatment. These oxygen-vacancies are known to be electron donors, determining the surface and electronic properties of TiO2201,202, which improve the charge transport in TiO2 as well as the electron transfer at the interface. To demonstrate the enhancement of the electronic properties, the resistance of the electrodes was measured, increasing in the following order: GF@TiO2

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Redox Flow Batteries Vanadium to Earth Quinones

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