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Figure 6.21. - Mechanism proposed for VRFB’s negative reaction using GF, GF@TiO2 and GF@TiO2:H as electrodes. In brief, TiO2:H based graphite felt electrode, as a low-cost, efficient and novel electrocatalyst towards the negative reaction was demonstrated to enhance the electrochemical performance in all-vanadium redox flow battery, especially at high charge/discharge rates. GF@TiO2:H electrodes showed greatly improved electrochemical properties (i.e. fast electron charge process) in combination with a better selectivity to V3+/V2+ reaction, inhibiting hydrogen-evolution reaction. Furthermore, the electronic donor properties 105PDF Image | Redox Flow Batteries Vanadium to Earth Quinones
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