New Phase-Change Thermal Energy Storage Materials for Buildings

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New Phase-Change Thermal Energy Storage Materials for Buildings ( new-phase-change-thermal-energy-storage-materials-buildings )

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- !IIll s-~•• TP-27,27 Thermal Condu~ii~ftyc (Wm K ) 1. 0 0.51 0.36 0.34 0.25 0.21 ~~ Name/Formula Tempera- t u r e (OC) E n t h a l p y (kJ/kg) Melting Tempera- t u r e (oC) 260 198 126 219 Specific H e a t a D e n s i t { (kJ/kg K) (kg/m- ) 2.84 1333 1218 2.75 1193 1118 2.76 1046 984 TME + graphite (10%) (weight basis) Solid/Liquid PCHs Calcium chloride cac12 6H2o Paraffin wax mixed commercial Conventional Materials Concrete Gypsum board 81 198 * 27 2.10 47 2.4 (a) Specific (CHtOH)tCH2CH3; ava lab e. 2 . MECHANISMS heat (c) of the low temperature temperature Table 1. Typical Properties of Thermal Storage Materials Transition Solid State PCMs Pentaerythritol 188 323 PE (CH 0H) c 24 Trimethylolethane 81 193 TME (CH 0H) CCH 233 Neopentyl glycol 43 NPG (CH 0H) C(CH ) 2232 T ris (hydroxymethyl) 2 126 acetic acid (CH 20H) 3CCOOH Composite SS PCMs NPG (60%) + TME (40%) 26 (molar basis) NPG (67%) + TMPb (33%) 24 (molar basis 131 204 76 61 174 191 128 polymorph; (b) TMP = Trimethylolpropane, polymorph and high temperature polymorph; * = data not high The SS PCMs listed in Table 1 derive their unusual behavior from their tetra- hedral molecular shape and the hydrogen resonant bonding that occurs between neighboring molecules in the crystalline solid. At low temperatures, the intermolecular hydrogen bonding restricts molecular movement. At the solid- state transformation temperature, the intermolecular hydrogen bonds break, allowing the molecules to rotate and vibrate more freely in their lattice sites (1). It is the energy absorbed by this increased molecular motion that imparts the heat storage capacity to these materials. Hhen the material is cooled, the reverse transformation occurs at the same temperature. The prevalence of intermolecular hydrogen bonds largely controls the amount of energy absorbed at the solid-state transition. By selecting the molecular structure or by mixing molecules of different structure in the same crystal- 2 140 2.64 1071 0.23 ** 1257 0.64 1196 0.43 1802 1.09 1562 0.54 770 0.12 0.19 102 ir *** 1. 82 1.085 755 0.11 0.92 2450

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