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Photochem 2022, 2 712 References molecules used for solar energy storage is required before this technology could provide an alternative and efficient way of harvesting and storing solar energy, as well as its use and release on demand. In the near future of MOST devices, the exploitation of hybrid strategies (multijunction devices) is the more promising field to improve the overall performance. Author Contributions: Bibliographic search and writing—original draft preparation, A.G.-G., L.M., N.S., B.P. and J.S.; writing—review and editing, R.L. and D.S.; supervision, R.L. and D.S.; funding acquisition, D.S. All authors have read and agreed to the published version of the manuscript. Funding: This research was funded by the Spanish Ministerio de Ciencia e Innovación, grant number PID2021-126075NB-I00. Institutional Review Board Statement: Not applicable. Informed Consent Statement: Not applicable. Data Availability Statement: Not applicable. Acknowledgments: A.G.-G., L.M., N.S., and B.P. thank the European Union’s H2020 research and innovation program under grant agreement No 951801. R.L. thanks Universidad de La Rioja and Ministerio de Universidades for his Margarita Salas grant. Conflicts of Interest: The authors declare no conflict of interest. 1. de Amorim, W.S.; Valduga, I.B.; Ribeiro, J.M.P.; Williamson, V.G.; Krauser, G.E.; Magtoto, M.K.; de Andrade Guerra, J.B.S.O. The nexus between water, energy, and food in the context of the global risks: An analysis of the interactions between food, water, and energy security. Environ. Impact Assess. Rev. 2018, 72, 1–11. [CrossRef] 2. Sun, C.-L.; Wang, C.; Boulatov, R. Applications of Photoswitches in the Storage of Solar Energy. ChemPhotoChem 2019, 3, 268–283. [CrossRef] 3. Wang, Z.; Erhart, P.; Li, T.; Zhang, Z.-Y.; Sampedro, D.; Hu, Z.; Wegner, H.A.; Brummel, O.; Libuda, J.; Nielsen, M.B.; et al. Storing energy with molecular photoisomers. Joule 2021, 5, 3116–3136. [CrossRef] 4. Lee, D.S.; Fahey, D.W.; Skowron, A.; Allen, M.R.; Burkhardt, U.; Chen, Q.; Doherty, S.J.; Freeman, S.; Forster, P.M.; Fuglestvedt, J.; et al. The contribution of global aviation to anthropogenic climate forcing for 2000 to 2018. Atmos. Environ. 2021, 244, 117834. [CrossRef] 5. IEA. Global Status Report for Buildings and Construction; International Energy Agency: Paris, France, 2019. 6. Rabaia, M.K.H.; Abdelkareem, M.A.; Sayed, E.T.; Elsaid, K.; Chae, K.J.; Wilberforce, T.; Olabi, A.G. Environmental impacts of solar energy systems: A review. Sci. Total Environ. 2021, 754, 141989. [CrossRef] 7. Xu, X.; Wang, G. Molecular Solar Thermal Systems towards Phase Change and Visible Light Photon Energy Storage. Small 2022, 18, 2107473. [CrossRef] 8. Ma, Q.; Wang, P.; Fan, J.; Klar, A. Underground solar energy storage via energy piles: An experimental study. Appl. Energy 2022, 306, 118042. [CrossRef] 9. Ma, Q.; Wang, P. Underground solar energy storage via energy piles. Appl. Energy 2020, 261, 114361. [CrossRef] 10. Wu, D.; Kong, G.; Liu, H.; Jiang, Q.; Yang, Q.; Kong, L. Performance of a full-scale energy pile for underground solar energy storage. Case Stud. Therm. Eng. 2021, 27, 101313. [CrossRef] 11. Wang, H.; Qi, C. Performance study of underground thermal storage in a solar-ground coupled heat pump system for residential buildings. Energy Build. 2008, 40, 1278–1286. [CrossRef] 12. Ciamician, G. The Photochemistry of the Future. Science 1912, 36, 385–394. [CrossRef] [PubMed] 13. Moth-Poulsen, K. Organic Synthesis and Molecular Engineering; Nielsen, M.B., Ed.; John Wiley & Sons, Inc.: Hoboken, NJ, USA, 2014; pp. 179–196. 14. Moth-Poulsen,K.;C ́oso,D.;Börjesson,K.;Vinokurov,N.;Meier,S.K.;Majumdar,A.;Vollhardt,K.P.C.;Segalman,R.A.Molecular solar thermal (MOST) energy storage and release system. Energy Environ. Sci. 2012, 5, 8534–8537. [CrossRef] 15. Zhang, Z.Y.; He, Y.; Wang, Z.; Xu, J.; Xie, M.; Tao, P.; Ji, D.; Moth-Poulsen, K.; Li, T. Photochemical Phase Transitions Enable Coharvesting of Photon Energy and Ambient Heat for Energetic Molecular Solar Thermal Batteries That Upgrade Thermal Energy. J. Am. Chem. Soc. 2020, 142, 12256–12264. [CrossRef] [PubMed] 16. Lennartson, A.; Roffey, A.; Moth-Poulsen, K. Designing photoswitches for molecular solar thermal energy storage. Tetrahedron Lett. 2015, 56, 1457–1465. [CrossRef] 17. Vlasceanu, A.; Broman, S.L.; Hansen, A.S.; Skov, A.B.; Cacciarini, M.; Kadziola, A.; Kjaergaard, H.G.; Mikkelsen, K.V.; Nielsen, M.B. Solar Thermal Energy Storage in a Photochromic Macrocycle. Chem.—A Eur. J. 2016, 22, 10796–10800. [CrossRef] 18. Yoshida, Z.-i. New molecular energy storage systems. J. Photochem. 1985, 29, 27–40. [CrossRef] 19. Gur, I.; Sawyer, K.; Prasher, R. Searching for a Better Thermal Battery. Science 2012, 335, 1454–1455. [CrossRef]PDF Image | Overview of Molecular Solar Thermal Energy Storage
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