Thermal energy storage: Recent developments

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Thermal energy storage: Recent developments ( thermal-energy-storage-recent-developments )

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H. Zhang et al./Progress in Energy and Combustion Science 53 (2016) 1–40 5 Fig. 3. Energy storage systems according to form of energy stored according to power rating and discharge period (adapted from Ref. 13). still need to be identified. By 2020, the goal is to have a specific in- vestment cost for thermo-chemical storage below 50 €/kWh. Towards 2030 the intention is to have thermo-chemical storage tanks for solar thermal power plants and industrial process heat applications. To take advantage of the high energy storage density, the operating tem- perature should exceed 400 °C [12]. 1.3. Energystorageingeneral,andthermalenergystorage specifically Energy storage, as suggested by its name, is to store a certain form of energy, which can thus be used later when necessary: the storage device is generally called an accumulator. Various forms of energy, commonly including kinetic energy, potential energy (gravi- tational), chemical energy, electrical energy or thermal energy, can be stored by using appropriate methods, as illustrated in Fig. 3. The different systems can be tentatively assessed in view of energy density and prices per unit energy-stored, as illustrated in Table 2. Table 2 Characteristics of different energy storage systems (adapted from Ref. 14). Storage mechanism High temperature thermal energy storage is the main objective of this paper, although cryogenics and moderate temperature storage will also be briefly dealt with. TES works by heating storage media during a charging period and then releasing the heat when the energy is needed [14], thus increasing the energy efficiency of a system and being commonly used to compensate the mismatch between energy supply and demand [15]. Current applications include thermal building pro- cesses [16]; solar applications such as cooking, solar water boilers, air heating systems, greenhouses and concentrated solar power plants [17–21]; mining and metallurgy [22,23]; and solar tower power plants [3,17]. 1.4. Heat balances in thermal energy storage Sensible heat storage (SHS) stores thermal energy by raising the temperature of a solid or liquid without the occurrence of a phase change. The following equation expresses the SHS potential: Pumped hydro energy storage (PHES) Compressed air energy storage (CAES) Flywheel energy storage system Superconducting energy storage system (SCESS) Superconducting magnetic energy storage (SMES) Lead-acid battery Nickel–cadmium (Ni—Cd) Lithium-ion (Li-ion) Sodium–sulphur (NaS) battery Sodium nickel chloride batteries (ZEBRA) Zinc–bromine flow battery (ZBB) Polysulphide–bromine flow battery (PSB) Vanadium redox battery (VRB) Hydrogen-based energy storage system (HESS) Combined powder loop + PCM Thermo-chemical storage (TCS) Mechanical Mechanical Mechanical Electrical Electrical Conventional battery Conventional battery Conventional battery Molten salt battery Molten salt battery Flow battery Flow battery Flow battery Chemical Thermal Thermal Storage period Day–month Day Hour Hour Hour Day–month Day Day–month Day–month Day–month Day–month Day–month Day–month Day–month Hour–week Hour–week Energy density (kWh/m3) 0.5–1.5 3–6 20–80 N/A 0.2–2.5 50–80 60–150 200–500 156–255 150–290 30–60 16–60 16–33 2.7–160 at 1–700 bar <150 1120–250 Price per unit energy- stored (€/kWh) 10–70 2–140 105–4 × 105 7 × 104–2.3 × 105 6.3 × 104–7.5 × 105 100–830 450–1800 500–2000 280–700 75-150 110–750 120–1000 110–750 2–15 1–20 8–100

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