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USAID GRID-SCALE ENERGY STORAGE TECHNOLOGIES PRIMER

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USAID GRID-SCALE ENERGY STORAGE TECHNOLOGIES PRIMER ( usaid-grid-scale-energy-storage-technologies-primer )

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Method Table 7. Methods for Producing Hydrogen Status Feedstock Description Gasification Mature Coal or biomass Air (or pure oxygen) and steam are used to initiate chemical reactions with the feedstock to create ‘syngas,’ a mixture of carbon monoxide and hydrogen and slag mineral residue. This syngas can be further refined through additional steam and catalysts to yield pure hydrogen. This process also yields several greenhouse gases such as CO2 and CO. The gas feedstock is heated to over 700°C in the presence of a catalyst producing syngas (carbon monoxide and hydrogen), which can be further refined to yield pure hydrogen gas. This process also yields several greenhouse gases such as CO2 and CO. Steam (Methane) Reforming Mature Natural gas or biogas Electrolysis Proton-Exchange Membrane Alkaline ° Solid Oxide Mature at scale R&D A proton-exchange membrane is used to split water in the presence of electricity. This process occurs at relatively low temperatures (70°–90°C). Pilot for at-scale production Electricity plus water A liquid alkaline solution of sodium or potassium hydroxide is used as the solution to generate hydrogen in the presence of electricity. This process occurs at relatively low temperatures (100°–150 C). A solid ceramic material is used as the electrolyte. This process must occur at relatively high temperatures (700°–800°C) but operates at a higher electrical efficiency. Photoelectrochemical Splitting R&D Solar energy plus water This process uses semiconductor materials (similar to those found in solar photovoltaic panels) to directly harness the energy from light to split water molecules. This process can occur in a panel-based reactor, in which the semiconductor material is submerged in water and generates electricity when exposed to light, which is used to generate hydrogen. Alternatively, semiconductor photocatalyst particles can be dispersed throughout a volume of water, which will generate hydrogen gas when exposed to sunlight. Thermochemical Splitting R&D High heat plus water This process uses high temperatures, either from nuclear waste heat or concentrated solar power (CSP), to drive chemical reactions in a closed loop to split water into hydrogen and oxygen. This process can be either direct (only using temperatures ~2,000°C) or hybrid (using lower temperatures, ~500 C, and electricity). Once produced, hydrogen can be stored and used later for electricit°y generation. Hydrogen can be stored as either a gas, liquid, or on the porous surfaces of nanostructures of certain materials. When stored as a gas, due to hydrogen’s low density, it must be stored in large, pressurized containers or at very low temperatures, which can complicate transportation and increase associated storage costs. Similar to natural gas and CAES, large underground caverns, such as retired salt mines, could be used to store high volumes of hydrogen gas. When stored as a liquid, the overall storage volume required decreases but storage costs may increase and efficiency may decrease. Finally, hydrogen atoms can be stored within the spaces inside metal or alloy lattices or on the surface of carbon structures (such as carbon nanotubes) (Sherif et al. 2014). The benefit of storing the hydrogen on the surface of or within other materials is that the hydrogen requires an energy input to release the hydrogen, providing some safety advantages to gaseous or liquid hydrogen. 31 This report is available at no cost from the National Renewable Energy Laboratory (NREL) at www.nrel.gov/publications.

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