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Solid sorbents are commonly found in nature and have been used for years to purify gases and liquids. Activated carbon, also called activated charcoal, is a form of carbon that has been processed to make it extremely porous, yielding a very large surface area available for adsorption. Activated carbon is widely used to purify gases, remove impurities from drinking water, filter impurities from aquarium systems, and even absorb poisons from digestive systems in medical applications. Zeolites, also found in nature, are crystalline aluminosilicates with porous structures. Synthetic versions of these materials have been made with oxide structures containing elements other than aluminum and silicon; however, all zeolites have well-defined pore structures. The metal atoms in zeolites are surrounded by four oxygens in a tetrahedron geometry. The crystalline materials stack into regular arrays, forming channels that permit gas permeation. Depending upon the atoms and structures used in these materials, the sizes and shapes of these channels can be tuned to specific dimensions and can permit selective passage of different gases, like a virtual “molecular sieve.” To date, thousands of zeolites have been reported based on hundreds of structures. Three types of structures are shown below that illustrate the channels that can form in these materials. (For more information, see International Zeolite Association Structure Commission, http://www.iza-structure.org/.) ABW MAZ Zeolites and Activated Carbon Zeolite structures. The ABW, MAZ, and CHA structures are three of thousands catalogued by the Structure Commission of the International Zeolite Association in an Internet database of zeolite structures. The commission assigned three-letter framework type codes to all unique, confirmed framework topologies. Source: www.iza- structure.org CHA 18PDF Image | 2020 Carbon Capture
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