2020 Carbon Capture

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2020 Carbon Capture ( 2020-carbon-capture )

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The permeability coefficient of a membrane material for a specific gas is defined as the steady-state flux of the gas through a unit thickness of the membrane under a unit partial pressure driving force. A related parameter used to describe the rate at which gas is transported through a particular membrane is permeance, defined as steady-state gas flux divided by the partial pressure driving force, which is equal to the permeability of a material divided by the membrane thickness. Thus membrane permeance can be increased by either using a higher-permeability material or reducing the membrane thickness. Solution-Diffusion Mechanism Permeability is a key factor in the solution-diffusion mechanism that governs the transport of small gas molecules through all polymers currently used as gas separation membranes. In this model, gas molecules first dissolve into the upstream face of a membrane (at high pressure) and then diffuse through the membrane in the direction of decreasing gas partial pressure and desorb from the lower-pressure downstream face of the membrane, as shown in the illustration.3,4 Within this framework, permeability is a function of the gas solubility (which links the gas concentration in the membrane to the pressure in the adjacent gas phase) and the diffusion coefficient of the gas in the membrane (which is a measure of the gas mobility). The ability of a membrane to separate two gases (e.g., CO2 and N2) is often characterized in terms of the ideal selectivity, defined as the ratio of the gas permeabilities. Because permeability is equal to solubility times diffusivity, and selectivity is the ratio of permability coefficients, the membrane selectivity is a function of both solubility selectivity and the diffusion (or mobility) selectivity. Upstream pressure p feed Downstream pressure p perm JA Membrane thickness  pfeed > pperm Component A Component B (1) Sorption on upstream side (2) Diffusion down partial pressure gradient (3) Desorption on downstream side • FluxofA≡JA =PA(pfeed,A-pperm,A)  • PermeabilityofA≡PA =DASA, where DA ≡ Diffusion coefficient of A SA ≡ Solubility coefficient of A PA DA  SA  •Selectivity≡αA/B=PB =DBSB Mobility selectivity Solubility selectivity 28

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