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Conclusions Separation based on membranes offers extraordinary promise for low-energy, efficient, reliable and environmentally benign gas separation for carbon capture applications. However, to realize the full potential of this technology, basic research is urgently required to provide revolutionary new membrane materials with controlled architectures that can respond efficiently to alternative driving forces. Recent advances in the synthesis of tailored materials, especially those with nanoscale architectures and functionalities; characterization tools; and molecular simulation and modeling techniques provide unprecedented new opportunities to develop the next generation of high-performance, robust, scalable membranes for carbon capture processes. References 1. D. A. Doyle, J. M. Cabral, R. A. Pfuetzner, A. Kuo, J. M. Gulbis, S. L. Cohen, B. T. Chait, and R. MacKinnon, “The structure of the potassium channel: Molecular basis of K+ conduction and selectivity, Science 280, 69–77 (1998). 2. R. W. Baker, Membrane Technology and Applications, 2nd ed., John Wiley and Sons, New York, 2004. 3. J. G. Wijmans and R. W. Baker, “The solution-diffusion model: A review,” J. Membrane Sci. 107, 1–21 (1995). 4. S. Matteucci, Y. Yampolskii, B. D. Freeman, and I. Pinnau, “Transport of gases and vapors in glassy and rubbery polymers,” in eds. Y. P. Yampolskii, I. Pinnau, and B. D. Freeman, Materials Science of Membranes for Gas and Vapor Separation, John Wiley and Sons, New York, 1–47, 2006. 5. R. W. Baker and J. G. Wijmans, “Membrane separation of organic vapors from gas streams,” in eds. D. R. Paul and Y. P. Yampolskii, Polymeric Gas Separation Membranes, CRC Press, Boca Raton, Florida, 353–397, 1994. 6. B. D. Freeman and I. Pinnau, “Separation of gases using solubility-selective polymers,” Trends in Polymer Science 5, 167–173 (1997). 7. R. W. Baker, N. Yoshioka, J. M. Mohr, and A. J. Khan, “Separation of organic vapors from air,” J. Membrane Sci. 31, 259–271 (1987). 8. R. W. Baker, “Future directions of membrane gas separation technology,” Ind. Eng. Chem. Res. 41, 1393–1411 (2002). 9. H. Lin, E. V. Wagner, B. D. Freeman, L. G. Toy, and R. P. Gupta, “Plasticization- enhanced H2 purification using polymeric membranes,” Science 311, 639–642 (2006). 10. L. M. Robeson, B. D. Freeman, D. R. Paul, and B. W. Rowe, “An empirical correlation of gas permeability and permselectivity in polymers and its theoretical basis,” Journal of Membrane Science 341, 178–185 (2009). 11. D. W. Breck, Zeolite Molecular Sieves, Wiley–Interscience, New York, 1974. 12. R. C. Reid, J. M. Prausnitz, and T. K. Sherwood, The Properties of Gases and Liquids, 3rd ed., McGraw-Hill, New York, 1977. 13. J. W. Phair and S. P. S. Badwal, “Materials for separation membranes in hydrogen and oxygen production and future power generation,” Science and Technology of Advanced Materials 7, 792–805 (2006). 14. B. D. Freeman, “Basis of permeability/selectivity tradeoff relations in polymeric gas separation membranes,” Macromolecules 32, 375–380 (1999). 35PDF Image | 2020 Carbon Capture
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