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2020 Carbon Capture

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2020 Carbon Capture ( 2020-carbon-capture )

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1.0 Introduction A large body of evidence demonstrates that global temperatures are rising. Eleven of the past 12 years rank among the 12 warmest since the 1850s, when temperature began to be regularly recorded [1]. Many attribute t his r ecent g lobal w arming t o hu man i nfluence on a tmospheric c omposition, p articularly t he increaseincarbondioxide.Overthepastseveralhundredyears,atmosphericCO2 concentrationshave steadily i ncreased from t he p re-industrial level of 280 t o ov er 370 ppm . T he i ncreases i n C O2 concentrations a re a ttributed pr imarily t o bur ning of coal, o il a nd na tural g as f or e lectrical g eneration, transportation, i ndustrial a nd dom estic us es ( e.g. c ement manufacturers). I n 2007, hum an a ctivities emitted r oughly 37 G tCO2 to t he atmosphere, 85 % of w hich came f rom c ombusting f ossil fuels a s a primary energy source and the balance from changes in land cover [2, 3]. R oughly one-third of the 37 GtCO2 emitted in 2007 came from the United States and China [4]. If unabated, atmospheric CO2 levels will c ontinue t o i ncrease r apidly a nd, w ithin 50 y ears, m ay e xceed c oncentrations ne eded t o pr otect sensitive e cosystems a nd a void f looding i n l ow-lying coastal areas. To a ddress this challenge, a m ulti- pronged a pproach i s ne eded t o d ecrease C O2 emissions w hich i nclude e fficient pr oduction a nd us e of energy, solar power, wind energy, biomass utilization, switching to fuel sources with lower or negligible emissions, and carbon capture and storage (CCS). Carbon capture involves the separation of CO2 from an effluent stream and compressed to a liquid or supercritical state for transportation by pipeline. It is then injected into geologic reservoirs (e.g., oil and gas fields, deep saline aquifers) where the geologic structure and processes are expected to store the CO2 for thousands of y ears. C CS i s c urrently hi gh on a dministrative a nd l egislative a gendas w orldwide. I n July 2008, t he G 8 l eaders called for 20 C CS de monstrations a nnounced g lobally b y 2010. S ince then, many c ountries have i nvested si gnificant su ms t o i nitiate co mmercial-scale d emonstrations an d b egan developing policies to address legal and regulatory concerns about geologic storage. Capture standards for new facilities have been proposed in legislation in Europe and the United States. These proposals would set a performance standard (either in unit of CO2 per unit of energy or as a percentage-based reduction in overall CO2 emissions). In t he U nited S tates, t he majority o f 2 008 emissions f rom stationary so urces came from the electricity sector, primarily from coal-fired power plants [5]. A wide variety of industrial facilities also emit CO2 as a by- or co-product of the industrial processes inherent to their industry, such as ethanol fermentation, oil and gas refining, chemical (including ethylene and ethylene oxide) production, hydrogen production, as well as others such as pulp and paper, iron and steel, ammonia and fertilizer, and cement manufacturing. CO2 in exhaust streams is present to various extents, at various temperatures and pressures, and with various other constituents (e.g. NOx, SO2). Such a variety suggests that different markets for CO2 capture technologies might exist and that number of different technologies to capture CO2 will be necessary. A cost-effective technology that is flexible and robust to these different applications, however, is likely to be valued and more desirable than a niche-market counterpart. A typical taxonomy separates CO2 capture into three categories: (1) post-combustion, (2) pre-combustion, and (3) oxy-combustion capture [5]. Post-combustion capture separates CO2 from exhaust gases. Using coal as a fuel, pre-combustion cap ture en tails g asifying t he co al p rior to c ombustion in a process t hat produces a readily capture-able stream of CO2. The technology used for carbon capture in pre-combustion is similar to that used in the hydrogen industry. Oxy-combustion capture produces a relatively pure stream of CO2 and water vapor by burning the coal in pure oxygen, where nitrogen is separated from air prior to combustion. Processes that seek to capture 90% or more of the CO2 in the exhaust stream are being developed, bu t i t i s e qually i f not more i mportant t hat t his t reated s tream be c omposed a s much a s possible of the exhaust stream that would otherwise be emitted. The gigatons of CO2 that need to be captured necessitate the reuse o f an y cap ture m aterial. It is further crucial t o c onsider how the capture technology can sc ale w ith t he exhaust stream an d the am ount o f C O2 being e mitted. Similarly, th e Carbon Capture Factual Document 7

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