Amine Based CO2 Capture

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Amine Based CO2 Capture ( amine-based-co2-capture )

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MWEq. = Equivalent Steam Usage [MW] Heat − to − Electricity Efficiency = Energy Conversion Efficiency [dimensionless] CO2Flow = Flow Rate of CO2 Captured [lb CO2/hr] Enthalpy Steam Inlet = Enthaly of Steam at Reboiler Inlet [Btu/lb CO2] 2.97E−7 = Conversion Factor for Btu to MW [MW/[Btu/hr]] Updated Base Plant Cost Equations for the Case with CO2 Capture In past versions of the IECM, the costs of the equipment in the Base Plant depended on the gross power produced (MW) by the power plant. In the updated version of the IECM for cases with CO2 capture, the majority of equipment in the Base Plant is instead sized on the gross power produced (MW) plus the equivalent electrical loss (MW), which is called the Gross Power Produced Effective internally in the IECM. This new calculation accounts for the steam produced by the base plant that is not used to generate electricity but is instead used to regenerate amine in the CO2 capture system. The only exception is the Turbine Island, which is still sized based the gross power produced. The Turbine Island does not need be sized based on the equivalent electrical loss because it is not part of the set of equipment that produces steam. This adjustment more realistically captures the cost equations of the base plant equipment for cases with CO2 capture. Updated Amine Usage for the Advanced Capture System For the advanced amine-based CO2 capture system, the Nominal Sorbent Loss (lb/ton CO2) represents the amount of sorbent that has been lost due to unwanted polymerization and oxidation reactions. The total sorbent loss, which requires makeup sorbent (called Sorbent (lb/hr) on the Get Results, CO2 Capture, Diagram screen), represents the Nominal Sorbent Loss (lb/ ton CO2) minus the amount of CO2 regenerated in the reclaimer. 5.2.3 Menu Updates to the IECM CO2 Capture System Updated CO2 Capture, Config Menu The IECM CO2 Capture screens have been updated to include the changes listed in this document. The updated Advanced Amine process has been included in the Set Parameters, CO2 Capture, Config Menu, and the user can now select between traditional MEA and Advanced Amine (FG+). An additional update to the Set Parameters, CO2 Capture, Config Menu is the inclusion of a polishing unit intended to lower the SO2 concentration in the feed gas. SO2 can react with MEA to produce undesirable and irreversible byproducts, therefore causing a loss of amine in the system that requires makeup (NETL 2007). The polishing unit uses caustic to capture the SO2, reducing the cost of makeup chemicals. The user can choose whether or not to include the polishing unit. The updated Set Parameters, CO2 Capture, Config Menu is shown in Figure 7. Integrated Environmental Control Model - Technical Documentation • 43

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