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Technical Summary 39 Table TS.8. Costs for ocean storage at depths deeper than 3,000 m. Ocean storage method Costs (US$/tCO2 net injected) 100 km offshore 500 km offshore Fixed pipeline 6 31 Moving ship/platforma 12-14 13-16 a The costs for the moving ship option are for injection depths of 2,000-2,500 m. via pipelines) are not included in the cost of ocean storage. However, the costs of offshore pipelines or ships, plus any additional energy costs, are included in the ocean storage cost. The costs of ocean storage are summarized in Table TS.8. These numbers indicate that, for short distances, the fixed pipeline option would be cheaper. For larger distances, either the moving ship or the transport by ship to a platform with subsequent injection would be more attractive. Legal aspects and public perception Mineral carbonation: technology, impacts and costs Mineral carbonation refers to the fixation of CO2 using alkaline and alkaline-earth oxides, such as magnesium oxide (MgO) and calcium oxide (CaO), which are present in naturally occurring silicate rocks such as serpentine and olivine. Chemical reactions between these materials and CO2 produces compounds such as magnesium carbonate (MgCO3) and calcium carbonate (CaCO3, commonly known as limestone). The quantity of metal oxides in the silicate rocks that can be found in the earth’s crust exceeds the amounts needed to fix all the CO2 that would be produced by the combustion of all available fossil fuel reserves. These oxides are also present in small quantities in some industrial wastes, such as stainless steel slags and ashes. Mineral carbonation produces silica and carbonates that are stable over long time scales and can therefore be disposed of in areas such as silicate mines, or re-used for construction purposes (see Figure TS.10), although such re-use is likely to be small relative to the amounts produced. After carbonation, CO2 would not be released to the atmosphere. As a consequence, there would be little need to monitor the disposal sites and the associated risks would be very low. The storage potential is difficult to estimate at this early phase of development. It would be limited by the fraction of silicate reserves that can be technically exploited, by environmental issues such as the volume of product disposal, and by legal and societal constraints at the storage location. The global and regional treaties on the law of the sea and marine environment, such as the OSPAR and the London Convention discussed earlier in Section 5 for geological storage sites, also affect ocean storage, as they concern the ‘maritime area’. Both Conventions distinguish between the storage method employed and the purpose of storage to determine the legal status of ocean storage of CO2. As yet, however, no decision has been made about the legal status of intentional ocean storage. The very small number of public perception studies that have looked at the ocean storage of CO2 indicate that there is very little public awareness or knowledge of this subject. In the few studies conducted thus far, however, the public has expressed greater reservations about ocean storage than geological storage. These studies also indicate that the perception of ocean storage changed when more information was provided; in one study this led to increased acceptance of ocean storage, while in another study it led to less acceptance. The literature also notes that ‘significant opposition’ developed around a proposed CO2 release experiment in the Pacific Ocean. The process of mineral carbonation occurs naturally, where it is known as ‘weathering’. In nature, the process occurs very slowly; it must therefore be accelerated considerably to be a viable storage method for CO2 captured from anthropogenic sources. Research in the field of mineral carbonation therefore focuses on finding process routes that can achieve reaction rates viable for industrial purposes and make the reaction more energy-efficient. Mineral carbonation technology using natural silicates is in the research phase but some processes using industrial wastes are in the demonstration phase. 7. Mineral carbonation and industrial uses This section deals with two rather different options for CO2 storage. The first is mineral carbonation, which involves converting CO2 to solid inorganic carbonates using chemical reactions. The second option is the industrial use of CO2, either directly or as feedstock for production of various carbon-containing chemicals. A commercial process would require mining, crushing and milling of the mineral-bearing ores and their transport to a processing plant receiving a concentrated CO2 stream from a capture plant (see Figure TS.10). The carbonation processPDF Image | CARBON DIOXIDE CAPTURE AND STORAGE
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