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228 IPCC Special Report on Carbon dioxide Capture and Storage below). Such reactions may cause either mineral dissolution and potential breakdown of the rock (or cement) matrix or mineral precipitation and plugging of the pore system (and thus, reduction in permeability). A carbonate mineral formation effectively traps stored CO2 as an immobile solid phase (Section 5.2). If the mineralogical composition of the rock matrix is strongly dominated by quartz, geochemical reactions will be dominated by simple dissolution into the brine and CO2-water-rock reactions can be neglected. In this case, complex geochemical simulations of rock-water interactions will not be needed. However, for more complex mineralogies, sophisticated simulations, based on laboratory experimental data that use reservoir and caprock samples and native pore fluids, may be necessary to fully assess the potential effects of such reactions in more complex systems (Bachu et al., 1994; Czernichowski-Lauriol et al., 1996; Rochelle et al., 1999, 2004; Gunter et al., 2000). Studies of rock samples recovered from natural systems rich in CO2 can provide indications of what reactions might occur in the very long term (Pearce et al., 1996). Reactions in boreholes are considered by Crolet (1983), Rochelle et al. (2004) and Schremp and Roberson (1975). Natural CO2 reservoirs also allow sampling of solid and fluid reactants and reaction products, thus allowing formulation of geochemical models that can be verified with numerical simulations, further facilitating quantitative predictions of water-CO2-rock reactions (May, 1998). 5.4.1.5 Anthropogenic factors affecting storage integrity As discussed at greater length in Section 5.7.2, anthropogenic factors such as active or abandoned wells, mine shafts and subsurface production can impact storage security. Abandoned wells that penetrate the storage formation can be of particular concern because they may provide short circuits for CO2 to leak from the storage formation to the surface (Celia and Bachu, 2003; Gasda et al., 2004). Therefore, locating and assessing the condition of abandoned and active wells is an important component of site characterization. It is possible to locate abandoned wells with airborne magnetometer surveys. In most cases, abandoned wells will have metal casings, but this may not be the case for wells drilled long ago or those never completed for oil or gas production. Countries with oil and gas production will have at least some records of the more recently drilled wells, depth of wells and other information stored in a geographic database. The consistency and quality of record keeping of drilled wells (oil and gas, mining exploration and water) varies considerably, from excellent for recent wells to nonexistent, particularly for older wells (Stenhouse et al., 2004). 5.4.2 Performance prediction and optimization modelling Computer simulation also has a key role in the design and operation of field projects for underground injection of CO2. Predictions of the storage capacity of the site or the expected incremental recovery in enhanced recovery projects, are vital to an initial assessment of economic feasibility. In a similar vein, simulation can be used in tandem with economic assessments to optimize the location, number, design and depth of injection wells. For enhanced recovery projects, the timing of CO2 injection relative to production is vital to the success of the operation and the effect of various strategies can be assessed by simulation. Simulations of the long-term distribution of CO2 in the subsurface (e.g., migration rate and direction and rate of dissolution in the formation water) are important for the design of cost-effective monitoring programmes, since the results will influence the location of monitoring wells and the frequency of repeat measurements, such as for seismic, soil gas or water chemistry. During injection and monitoring operations, simulation models can be adjusted to match field observations and then used to assess the impact of possible operational changes, such as drilling new wells or altering injection rates, often with the goal of further improving recovery (in the context of hydrocarbon extraction) or of avoiding migration of CO2 past a likely spill-point. Section 5.2 described the important physical, chemical and geomechanical processes that must be considered when evaluating a storage project. Numerical simulators currently in use in the oil, gas and geothermal energy industries provide important subsets of the required capabilities. They have served as convenient starting points for recent and ongoing development efforts specifically targeted at modelling the geological storage of CO2. Many simulation codes have been used and adapted for this purpose (White, 1995; Nitao, 1996; White and Oostrom, 1997; Pruess et al., 1999; Lichtner, 2001; Steefel, 2001; Xu et al., 2003). Simulation codes are available for multiphase flow processes, chemical reactions and geomechanical changes, but most codes account for only a subset of these processes. Capabilities for a comprehensive treatment of different processes are limited at present. This is especially true for the coupling of multiphase fluid flow, geochemical reactions and (particularly) geomechanics, which are very important for the integrity of potential geological storage sites (Rutqvist and Tsang, 2002). Demonstrating that they can model the important physical and chemical processes accurately and reliably is necessary for establishing credibility as practical engineering tools. Recently, an analytical model developed for predicting the evolution of a plume of CO2 injected into a deep saline formation, as well as potential CO2 leakage rates through abandoned wells, has shown good matching with results obtained from the industry numerical simulator ECLIPSE (Celia et al., 2005; Nordbotten et al., 2005b). A code intercomparison study involving ten research groups from six countries was conducted recently to evaluate the capabilities and accuracy of numerical simulators for geological storage of greenhouse gases (Pruess et al., 2004). The test problems addressed CO2 storage in saline formations and oil and gas reservoirs. The results of the intercomparison were encouraging in that substantial agreement was found between results obtained with different simulators. However, there were also areas with only fair agreement, as well as somePDF Image | CARBON DIOXIDE CAPTURE AND STORAGE
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