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CO2 Liquid Vapor N2 O2 Figure 7 Three-phase N2-O2-CO2 at -55 °C and an average 129 atm. Data from [24] The compressed gases contain small amounts of oxygen in addition to carbon dioxide and nitrogen. The oxygen contents change (generally decrease) the size of the two-phase region shown in Figure 6. Typical three-component data appear in Figure 7, for conditions of an average 129 atm and -55 °C. The left side of this diagram represents 0% O2 and corresponds to the conditions in Figure 6 at 129 atm, as can be verified by checking the data. Increasing O2 concentrations decrease the composition range over which two phases form. However, the changes are not overly complex. That is, the O2, under these conditions, behaves much the same as an equivalent amount of extra nitrogen would behave. We have additional data at other pressures and temperatures. We are highly confident that we can provide thermodynamic models capable of predicting the two-phase regions for the three-component N2-CO2-O2 system, and the model predictions demonstrated above reasonably predict the two-phase region for the N2-CO2 system. However, we have not yet taken the time to regress the coefficients in the three- and higher-component models.PDF Image | CC Pittsburgh Coal Conference
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