Desalination Performance Assessment Anion-Exchange Membranes

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Membranes 2020, 10, 347 11 of 15 3.3. Energy Consumption Figure 8a–d shows the energy consumption and current density required to achieve a certain percentage of desalination as calculated from the performed experiments (considering only the electrical component and not the pumping). The energy density needed to reach 90% (or close to 90% in the case of fireclay) desalination was notably lower for NaCl with both Siltep 11 and foamed fireclay, as expected due to the size and charge of SO42−. After reaching desalination of 99%, the energy requirements for additional desalination rise steeply. Further increments in applied current and voltage also caused heating of the unit, mainly apparent in the electrode streams, in which the temperature increased up to 40 ◦C while the unit got warm to the touch. Lowering the energy demand for production of very diluted (>99%) water could be possible by splitting the process into multiple stages in series, a method that is used in commonly employed desalination technologies and was tested for the first time with SED by [18]. Despite the suboptimal choice of porous material (especially regarding the combination of surface charge and choice of membranes) and the energy losses due to heat generation, the energy consumption is comparable to experiments performed on glass frit and in much smaller volumes by [20]. This observation is interesting from the scale-up point of view. The larger cross-sectional area of the frit used in our unit decreases energy consumption as, according to Ohm’s law, the power P is inversely proportional to the cross-sectional area (P = I2R, where resistivity R ~ L/A; L being the length of the resistive material and A the cross-sectional area). Comparison between the L/A ratio of the porous material of our unit (L/A = 10/5000 mm−1 = 0.002 mm−1) and the glass frit in early SED unit by [20] (L/A = 2.7/200 mm−1 = 0.0135 mm−1), unveils the reason behind similar energy density even at two orders of magnitude higher flow rates, which drives the energy requirements up (the current I is proportional to flow rate Q for the same dimensionless current according to Equation (1) and, therefore, E = P/Q ~ QL/A [18]). Although the power consumption was still significant, this study was not primarily focused on its reduction, and the main components to affect it remain largely unoptimized. 3.4. Porous Media Choice and Shape The theoretical and experimental work published previously suggests the usage of porous materials with close to 1 μm pore size to sustain deionization shocks in the OLC region [4,13,16,20]. Larger pores (approximately >10 μm) may lead to convective mixing that may interrupt the shock formation and produce instabilities inside the porous material. However, such a small pore size (around 1 μm) is inevitably connected with high hydrodynamic resistivity. Therefore, low volume flow rates or increasing energy demand for pumping seem to be the downsides of the previously described SED devices [21]. As the purpose of this scale-up was to increase the production of freshwater, it was necessary to consider the usage of materials with higher solution throughput, possibly even with lower effectivity in the beginning. Therefore, two types of porous ceramics with different pore sizes that were both more than one order of magnitude larger compared to pores of the glass frit used in [4,16–20] (and different enough one from the other) were chosen for this study. The solution throughput was also related to the increased dimensions of the porous material, especially in the direction of the solution flow, which only added to the hydrodynamic resistivity of the material. On the other hand, this increase was made with an idea of a longer flow trajectory that would provide more space and therefore require lower currents for the shock to propagate, as also [18] suggests and discusses. For further scale-up, widening the porous medium (and the whole unit) could also be beneficial in order to increase the cross-sectional area and the functional membrane area. The size, shape, and morphology significantly affected power consumption.

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