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Electrodialysis for water desalination

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Electrodialysis for water desalination ( electrodialysis-water-desalination )

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Special ion exchange membranes have also been developed through several research efforts focused on the optimal tuning of membrane properties. These efforts led to special membranes characterised by hybrid structures and particular manufacturing methods [66, 77]. Interpenetrating (IPN) and semi- interpenetrating (sIPN) polymer network IEMs are examples [98–103]. IPN are prepared by mixing two polymers that cross-link due to permanent entanglement, while sIPN are composed by a linear or branched polyelectrolyte immobilised in a cross-linked polymer matrix. This particular structure allows electrochemical and mechanical properties to be tailored for specific applications [98, 103]. Membranes prepared by radiation grafting represent another class of IEMs, in which this new technique allows incompatible polymers to be linked, thus combining their properties. In addition, these properties can easily be tuned by choosing the degree of grafting [66]. Several works deal with the preparation and characterisation of IEMs through the grafting method, and the possibility of using them in ED has been assessed [104–108]. The last group of special membranes is represented by the hybrid organic-inorganic IEMs. Combining the properties of polymers with those of inorganic materials, chemical, mechanical and thermal stability can be significantly enhanced [77]. For this reason, these membranes are mainly used in fuel cell applications [109–117]. Hybrid structures are usually obtained through intercalation, blending, in situ polymerization, molecular self-assembling or sol–gel process, with this latter being the most widespread method [118, 119]. A particular development has led to special membranes incorporating both positive and negative fixed charges within the same membrane [77]. Bipolar membranes (BPM) are the most remarkable example of this class. BPM are constituted of an anion exchange layer overlapped with a cation exchange layer. These membranes are mainly used in a special application of electrodialysis, where water splitting is induced to produce acid and alkaline solutions [57, 77]. Bipolar membranes can be manufactured by different methods such as casting a cation exchange polyelectrolyte solution on an anion exchange membrane (or vice versa) [120], adhering commercial cation and anion exchange membranes [23], or functionalizing the two sides of a standard membrane [121–124]. Two other interesting classes of membranes containing both type of charges are the amphoteric and the mosaic membranes [77]. The former present randomly distributed weak acid and weak basic groups. Their main feature is that charged groups respond to pH variations, thus modifying the cationic or anionic selective character of the membrane. This makes amphoteric membranes particularly useful in special applications such as in biomedical and industrial fields [77]. 16

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