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Electrodialysis for water desalination

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Electrodialysis for water desalination ( electrodialysis-water-desalination )

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layer formation and concentration polarisation. In addition, the presence of DC leads to concentration polarisation in the internal pores even when the external diffusion layers are not present [147]. Finally the blank resistance to be subtracted in order to separate the resistance of the membrane from that of the solution can be relatively very high for low concentration, thus affecting the accuracy of the method. As an alternative to DC-based methods, AC-based measurements can be performed adopting the Electrical Impedance Spectroscopy (EIS) method, able to distinguish among the contributions due to Ohmic effects, electric double layer and diffusion boundary layer and, thus, to estimate the pure membrane resistance [75, 142, 148, 149]. On the other hand, EIS is the most complex methodology, as it requires the identification and implementation of an “electrical model” fully describing all phenomena involved, in order to properly interpret the experimental data and convert them into the desired information. 3.4 Fouling and electrodialysis with polarity reversal (EDR) Although ED is not generally affected by fouling and scaling phenomena as much as other desalination processes such as RO [150], IEMs fouling can still be a limiting factor for maintaining good process performances. In particular, this phenomenon can significantly enhance membrane resistance and pressure drops along the channel and, in some cases, even reduce membrane permselectivity [151]. I-V curves are often used to characterise membrane fouling, though this method does not provide information on the properties of fouling layers. EIS has been proposed as a supplementary investigation method in order to capture more details on interfacial layers [152]. Three main classes of fouling compounds can be identified: scalants, colloidal particles and organic materials [153]. Scaling is one of the most important problems in desalination, especially when the feed water is rich in low-solubility salts such as CaCO3 and CaSO4. The most common methods for reducing it include the use of lower recovery rate, the adjustment of pH and cleaning procedures with citric acid or EDTA [153]. In addition, the possibility of treating the concentrate stream (i.e. the one with highest scaling potential) of a batch ED unit by magnetic or ultrasonic field has been reported [154]. In particular, the magnetic field was applied to a part of the feeding line, while an ultrasonic bath was used as the concentrate tank. Interestingly, the last method not only results in a scaling reduction but also in an improvement of ions transport. 20

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