Electrodialysis for water desalination

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Electrodialysis for water desalination ( electrodialysis-water-desalination )

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polarity of the electrodes at regular time intervals [163]. Consequently, diluate and concentrate channels are inverted and the reverse electric field promotes the periodic removal of electrically- charged foulants (e.g. colloids or organic matter) deposited on membranes surface. In this way, detached particles are entrained by the flowing solutions and discharged with the exiting streams (“off-specification” outlet), which are therefore disposed back to the sea (or to another receiving body) for a time interval allowing the complete cleaning of the feed compartments, typically ranging from a few seconds up to 1-2 minutes [163]. EDR adds complexity to the process as it requires a triggering control unit, electric control systems to change polarity and automatic valves for compartments switching . In addition, some of the feed is wasted during the “off-spec transition”, which leads to a reduction in the conversion rate of the process. Nevertheless, EDR offers significant advantages in terms of minimisation of cleaning procedures and pre-treatments and avoids the presence of acids tanks, complexing agents tanks, dosing pumps and pH controllers inside the desalination plant [163]. Moreover, the polarity reversal technology is able to operate under extreme conditions, such as salt supersaturation, with examples of plants operating under a super-saturation level of CaSO4 higher than 175% [164]. More importantly, EDR has allowed the operation of brackish water ED industrial plants for more than 30 years, with IEMs lifetime reaching up to 10-15 years. More recently, a concept similar to polarity reversal has been investigated, namely the pulsed electrical field (PEF) [153, 165, 166]. The PEF operating mode consists of discontinuously applying the electric field and generating a constant current, leaving some time intervals without any electric field applied. This method is claimed to reduce membrane fouling, thus increasing process performances, by disturbing the deposition of charged species. In addition, a reduction of the polarisation layer has also been experienced [165, 166]. PEF has been recently compared with EDR, showing similar performances or even lower energy consumption under certain conditions [167]. 4. Hydrodynamics and mass transport in electrodialysis: from fundamentals to recent developments The role of hydrodynamics and associated phenomena of mass transport is crucial in determining the performance of ED stacks and the capital and operating costs of the process. It is well known that mass transfer limitations and non-Ohmic voltage drops arise because of the so called “concentration polarization phenomena” and can be mitigated by convective motions enhancing mixing. The energetic cost of the process may also be affected by the power consumption for pumping the solutions through the channels. Moreover, the channel features, which are essential for 22

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