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Electrodialysis for water desalination

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Electrodialysis for water desalination ( electrodialysis-water-desalination )

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become more pronounced and cause a deviation from the linear trend. A much lower slope characterises region II, which can be regarded as a transition step following the achievement of the limiting current, conventionally identified by the intersection between the line tangent at the first tract of the current-voltage curve and the tangent of the plateau (or at the inflection point) in region II. Then, the slope increases again towards region III until reaching an asymptotic value leading to a stable linear increase of current vs voltage. I II III ilim Voltage drop due to concentration polarization Voltage Figure 7. Sketch of a typical current-voltage curve for an IEM immersed in an electrolyte solution, showing a limiting current density and the presence of three distinct regions. The behaviour of IEMs in current-voltage tests has been explained by the effects of the conductive heterogeneity of the membrane surface [138, 207, 208, 211–216], which can be viewed as a mosaic of alternating conductive and insulating regions of size ranging from micrometers to tens of micrometers. Therefore, for any given average current density, the local current density on the conductive areas is larger. This results in a decrease in the average value of ilim compared to a membrane having an electrically homogeneous surface, or to a metal plate electrode. Hence, region II of the current-voltage chart is due to a gradual achievement of the local ilim in the non-conductive regions, at the cost of a much larger voltage drop. Another effect of the conductive heterogeneity is the alteration (elongation or shortening, depending on the distance between the surface heterogeneities) of the plateau length, i.e. of the onset of the overlimiting transport phenomena, namely electroconvection, associated to the generation of a non-uniform electric field with tangential components. Also geometrical heterogeneities of the membrane surface affect current-voltage curve features such as the ilim value, the plateau length and the amount of overlimiting transport through electroconvection. Profiled membranes may enhance the mass transfer rate by the increase in the membrane active area, the promotion of fluid mixing and the increase of electroconvective mixing due to larger tangential components of driving force [217]. More recent studies [173, 217–219] have 28 Current density

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