Electrodialysis for water desalination

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Electrodialysis for water desalination ( electrodialysis-water-desalination )

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In scRED mode the RED unit external load is short-circuited, thus renouncing to energy production in order to maximise the salt transfer rate from the concentrate to the dilute compartment, thus enhancing the dilution effect. In ARED mode the ionic current inside the scRED unit is further increased by applying an additional external electrical potential to the RED unit, consuming energy in order to “assist” the dilution process, exceeding the maximum achievable current in scRED. In both cases, the arising benefits are more suitable for the first coupling configuration, where dilution plays a fundamental role in reducing the overall energy consumption, rather than in the second, where dilution is considered beneficial only for environmental reasons. Due to the complex nature of such processes, it is not possible to determine a priori which of the configurations or RED operation mode is the most convenient to achieve the overall minimum energy consumption. In addition to that, pushing the dilution process to high levels will significantly increase the capital costs, mainly depending on the amount of membrane area required. For this reason, optimisation studies are crucial for the development of such hybrid schemes. In the current literature, the RED-RO coupling has been investigated by several authors, although still at a conceptual level [411–414]. In particular, Li et al. [411] explored the RED-RO process through a simple mathematical model, showing that the process can potentially achieve a ~50% lower energy consumption compared to state-of-the-art seawater RO. Vanoppen et al. [409] performed a comparative analysis of all RED operational modes coupled to RO, exploring the operational ranges and identifying the benefits in energy consumption reduction. Specific energy consumption below 1 kWh/m3 were theoretically demonstrated to be feasible, although an important increase of overall membrane area required (including RED membranes) was found in these scenarios. The RED-ED process has been much less studied, with only one recent publication by Wang et al. [415] who focused on the very specific case of desalination of high salinity waste brine containing phenols. They demonstrated an overall reduction of energy consumption of about 30% compared to the stand-alone ED case, though such figures can not be compared with RO, due to the much higher energy consumption of the base case (above 20 kWh/m3). It should be noted that, as an alternative to the reverse electrodialysis dilution process, other osmotically-driven processes such as Pressure Retarded Osmosis [414, 416] have been proposed in the literature. Similarly to the RED case, forward osmosis [417–420] and pressure-assisted osmosis [417] have also been proposed for further enhancing the dilution process in order to reduce the overall desalination energy consumption. 77

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