Shock Electrodialysis for Water Purification and Electrostatic Correlations

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Shock Electrodialysis for Water Purification and Electrostatic Correlations ( shock-electrodialysis-water-purification-and-electrostatic-c )

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List of Figures 1-1 Energy required to remove 99% of the ions from an ideal NaCl solution of a given concentration at various water recovery ratios. . . . . . . . 31 1-2 Regimes of Concentration Polarization. Reprinted with permission from Mani et al [68]. Copyright 2009 American Chemical Society. . . 36 2-1 Diagram showing the architecture and operating principles of the shock electrodialysis prototype. The anode and cathode reactions shown are for the water splitting reaction that occurs in the prototype. However, other reactions may also occur, especially at the anode, where the presence of chloride ions may cause the oxidation of chloride ions to hypochloriteionsorchlorinegas. .................... 47 2-2 Diagram showing how the prototype may easily be scaled up. . . . . . 48 2-3 Picture of the first prototype with a somewhat stiff silicone gasketing material (in blue). Unfortunately, the 3-D arrangement of the screws did not allow for adequate compression of the middle section containing theporousmedium............................. 50 2-4 Picture of the inside of the second prototype with, in this case, a very soft silicone gasketing material. In addition to the silicone being too soft, the prototype had the challenge that, while vertical compression of the device was now possible, an adequate seal of the sides of the porousmediumwasstilldifficulttoachieve. . . . . . . . . . . . . . . 51 2-5 Photographs of the shock electrodialysis prototype to show the place- mentofvariouscomponentswithinthedevice. . . . . . . . . . . . . . 52 11

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