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Figure 5-6: Difference in potential as a function of MgCl2 concentration for PLL of a molecular weight of 150000-300000 g/mol. Electrolyte KCl KNO3 MgCl2 ρb (C/m3 ) lc /lB lc (Å) L (nm) εp /ε0 937.31 1.7080 11.576 815.01 82.697 2039.0 1.3066 5.1401 374.66 142.48 1079.3 2.0933 10.012 707.78 117.19 Table 5.2: Parameters for 150000-300000 g/mol. various electrolytes with PLL of a molecular weight of charge between the magnesium ion and the singly charged dissociated silanol groups on the surface. Figure 5-6 shows the model prediction for this electrolyte and table 5.2 shows a comparison of the parameters for various electrolytes with heavy PLL chains. Overall, the results we obtain for varying electrolytes are very interesting. We al- ready see from figures 5-4 – 5-6. We observe that an increase in the background charge density is accompanied by a decrease in correlation length and thickness and an in- crease in dielectric constant. Furthermore, we observe that the concentration at which ∆φs changes signs also increases as the background charge density increases. These 129PDF Image | Shock Electrodialysis for Water Purification and Electrostatic Correlations
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