Green synthesis of silver nanoparticle Oscillatoria extract

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Green synthesis of silver nanoparticle Oscillatoria extract ( green-synthesis-silver-nanoparticle-oscillatoria-extract )

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B. Adebayo-Tayo et al. Heliyon 5 (2019) e02502 3427.95 cm1 was more prominent than other peaks and it showed the presence of hydroxyl (OH) stretch of alcohol. The peak 1648.10 cm1 suggested the presence of benzene. The peaks 1019.34 cm-1and 952.97 cm1 indicate the presence of hetero oxy compounds in which 1019.34 cm1 is an aliphatic phosphate with P–O–C stretch while 952.97 cm1 is an aromatic phosphate compound. However, the peak 902.37 cm1 is also an aromatic phosphate compound but not a hetero oxy compound. Peak 709.72 cm1 is a hydroxyl compound that was out of plane bend and peak 675.62 cm1 indicates the presence of an aryl thioether com- pound with C–S stretch that is a sulphate ion. 3.4. Scanning electron microscopy (SEM) Morphological identification of the biosynthesized silver nano- particles was determined using scanning electron microscopy. The scanning electron micrograph confirmed the shape of the biosynthesized OsSNPs to be spherical and 10 nm in size (Fig. 4). 3.5. Thermogravimetry (TGA) Thermal stability in relative to weight of the biosynthesized silver nanoparticles was assessed using Thermogravimetry (TGA). It was observed from the TGA curve that dominant weight loss of the SNPs of Oscillatoria sp. extract occurred in temperature region between 350 C and 450 C (Fig. 5). There was little weight loss below 350 C and above 450 C. Fig. 5. TGA thermograph of the biosynthesized silver nanoparticles. 3.6. Particle size and distribution of the OsSNPs The DLS is used to determine the diameter of nanoparticles dispersed in liquid. It also determines the size of particles and their distribution in physiological solutions [38]. The size distribution histogram of dynamic light scattering (DLS) analysis of the OsSNPs shows the particle diameter Fig. 3. FTIR spectrum of the biosynthesized silver nanoparticles. Fig. 4. a & b. SEM and 3D image of the biosynthesized silver nanoparticles. 4

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