Microwave Irradiation Synthesis Silver Nanoparticle

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Microwave Irradiation Synthesis Silver Nanoparticle ( microwave-irradiation-synthesis-silver-nanoparticle )

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Polymers 2020, 12, 1155 7 of 16 Polymers 2020, 12, x FOR PEER REVIEW 7 of 16 Figure 3.. CC1s1asnadnAd gA3dg3XdPXS PspSescptreactorfa(ao)fG(aO), G(bO) ,R(GbO) -RAGgON-PAsg, N(c)PRs,G(Oc)-ARgGNOP-sA-(gPNS-PPsM-(PMSA-P)M, (Md)AR)-, (dG)OR--((PGSO-P-M(PMS-APM)-AMgAN)-PAs,g(Ne)PAs,g(Ne)PAs,gaNnPds,(fa)ntdhe(fn)atnhoecnoamnpocoosmitepso. sites. 3.4. Raman Spectroscopy 3.4. Raman Spectroscopy The covalent modification of RGO nanosheets can be evaluated using Raman spectroscopy [43,44]. The covalent modification of RGO nanosheets can be evaluated using Raman spectroscopy As shown in Figure 4, the main scattered peaks for PS were observed at 1603 and 1585 cm-1, while for [43,44]. As shown in Figure 4, the main scattered peaks for PS were observed at 1603 and 1585 cm-1, PMMA, the peak was at 1728 cm−1. These peaks correspond to the stretching of phenyl of the PS and while for PMMA, the peak was at 1728 cm−1. These peaks correspond to the stretching of phenyl of the carbonyl groups (C=O) of the PMMA, respectively. Besides, the observed characteristic peaks for the PS and the carbonyl groups (C=O) of the PMMA, respectively. Besides, the observed characteristic graphene were detected at ~1350 cm−1 (D band) and ~1595 cm−1 (G band). These D and G bands are peaks for graphene were detected at ~1350 cm−1 (D band) and ~1595 cm−1 (G band). These D and G related to the sp3 and sp2 states of the carbon group in graphene and can confirm the successful thermal bands are related to the sp3 and sp2 states of the carbon group in graphene and can confirm the exfoliation of the graphene sheets [38]. As observed in Figure 4, the intensity ratios of D/G bands are successful thermal exfoliation of the graphene sheets [38]. As observed in Figure 4, the intensity ratios 1.46 for RGO/AgNPs, 1.09 for RGO/AgNPs-(PS-PMMA), and 1.33 for R-(GO-(PS-PMMA))/AgNPs. of D/G bands are 1.46 for RGO/AgNPs, 1.09 for RGO/AgNPs-(PS-PMMA), and 1.33 for R-(GO-(PS- The attainment of a higher D/G ratio suggests better exfoliation of the graphene sheets. Therefore, PMMA))/AgNPs. The attainment of a higher D/G ratio suggests better exfoliation of the graphene the MWI-prepared nanocomposite displayed better dispersion of the RGO/AgNPs within the PS-PMMA sheets. Therefore, the MWI-prepared nanocomposite displayed better dispersion of the RGO/AgNPs matrix compared to that of the in situ-prepared nanocomposite. This enhancement of the D/G intensity within the PS-PMMA matrix compared to that of the in situ-prepared nanocomposite. This ratio can be correlated to the conversion of sp2-hybridized carbon to the sp3 state due to the covalent enhancement of the D/G intensity ratio can be correlated to the conversion of sp2-hybridized carbon interaction between RGO/AgNPs and the polymer matrix [45]. to the sp3 state due to the covalent interaction between RGO/AgNPs and the polymer matrix [45].

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