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Spinning Disk Reactor Nano Production Intensification

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Spinning Disk Reactor Nano Production Intensification ( spinning-disk-reactor-nano-production-intensification )

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Nanomaterials 2020, 10, 1321 Nanomaterials 2020, 10, x FOR PEER REVIEW 9 of 15 9 of 15 (b) Figure 4. Structure of nZNO obtained in run 23 (a), and 8 (b) (EHT = 20.00 kV, Mag = 160.00kx, WD = Figure 4. Structure of nZNO obtained in run 23 (a), and 8 (b) (EHT = 20.00 kV, Mag = 160.00kx, 9.5 mm). WD = 9.5 mm). 4. Discussion The influence of ri on the nZnO particles and total flowrate on the rotating disk was clearly visible in Figure 2. Indeed, the optimal values were 2.5 cm for ri and 0.05 L/min for QZn, i.e., 0.1 L/min as the total flowrate. These two parameters strongly influenced the fluid dynamic conditions established in the rotating liquid film, which was generated onto the surface of the disk [46]. The residence time τ [s] on the disk can be calculated as [37]: 1/3 􏰎 81π2υ 􏰏 τ= 16ω2Q2 􏰧 4/3 4/3􏰨 rd −ri (2) where Q is the total inlet flowrate [m3/s], ν is the kinematic viscosity [m2/s], assumed equal to that of water being the diluted solution, and rd [m] is the disk radius. Figure 5 summarizes the influence of ri on residence time. The increase of ri and Q caused a decrease in the reagents residence time on the rotating disk surface; therefore, τ being too low, or Q too large, may hinder completion of the reaction. Usually, these kind of precipitation reactions performed by the SDR are very rapid [38], with induction times lower than 1–1.5 ms. Therefore, the influence of the analyzed parameters on the reaction yield was quite limited within the investigated range. Indeed, at fixed ri, an increase in Q caused a yield reduction of approximately 1–3% (see Table 2), whereas when maintaining Q as constant, an increase in ri led to a yield reduction of 1–2%. These parameters also influenced the average dimension of the obtained nanoparticles, mainly due to the different specific power values dispersed in the rotating liquid film ε [W/kg] and mixing time τmix [s], as already observed in previous works [10,24]: 1􏰳􏰧22 2􏰨 􏰧22 2􏰨 􏰴 ε=2τωr+vr out−ωr+vr feed (3) 􏰩υ􏰪0.5 τmix = 12 ε (4)

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