Electrode Materials for Sodium-Ion Batteries

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Electrode Materials for Sodium-Ion Batteries ( electrode-materials-sodium-ion-batteries )

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Materials 2020, 13, 3453 16 of 58 Table 1. Electrochemical properties of selected cathode-materials reviewed in the text, including P2-layered oxide materials (from ref. [43–81]), O3-layered oxide materials (from ref. [85–93]), another oxide (V2O5), polyanionic compounds (from ref. [107–131]), Prussian blue analogs (from ref. [168–175]). Active Material Na0.7CoO2 spheres (5 μm) Na0.7CoO2 nanosheets Na0.67Ni0.25Mg0.1Mn0.65O2 Na0.5[Ni0.23Fe0.13Mn0.63]O2 Na0.85Li0.17Ni0.21Mn0.64O2 Zn-doped Na0.833[Li0.25Mn0.75]O2 Na0.7Mg0.05[Mn0.6Ni0.2Mg0.15]O2 Na0.66Co0.5Mn0.5O2 Na2/3Li1/9Ni5/18Mn2/3O2 C-coated NaCrO2 Na0.9[Cu0.22Fe0.30Mn0.48]O2 Na[Ni0.58Co0.06Mn0.36]O2 Na0.75Ni0.82Co0.12Mn0.06O2 NaMn0.48Ni0.2Fe0.3Mg0.02O2 V2O5 nanosheet array Na V (PO ) 3 2 43 Na3V2(PO4)3/C Na3V2(PO4)3/C loading 3.5 mg cm−2 Reversible Capacity 125 mA·h·g−1 at 0.04C 1.16 mA·h·cm−2 at 1C 100 mA·h·g−1 at C/10 200 mA·h·g−1 at 15 mA·h·g−1 (C/10) 95–100 mA·h·g−1 at C/10 162 mA·h·g−1 at 0.2C 70 mA·h·g−1 at 1C 86.5 mA·h·g−1 at 10C 72.2 mA·h·g−1 at 20C 120 mA·h·g−1 at 20 mA·h·g−1 99 mA·h·g−1 at 150C 100 mA·h·g−1 electrode at 0.1C 157 mA·h·g−1 at 15 mA·g−1 132.6 mA·h·g−1 at 10C 80 mA·h·g−1 at 1C 136 mA·h·g−1 at 0.1C 241 mA·h·g−1 at 50 mA·g−1 77 mA·h·g−1 at 1 A·g−1 115 mA·h·g−1 at 0.2C 38mA·h·g−1at500C 86 mA·h·g−1 at 100C 96.8 mA·h·g−1 at 100C 69.9 mA·h·g−1 at 200C Capacity Retention Ref. 86% at 0.4C after 300 cycles [43] 50 mA·h·g−1 at 6C after 1100 cycles [44] 87% at C/10 after 100 cycles [51] 125 mA·h·g−1 at 100 mA·g−1 after 100 cycles [59] 98% at C/10 after 50 cycles Stable at 0.2C over 200 cycles 79% at 1C after 1000 cycles 78.9 mA·h·g−1 at 10C over 100 cycles 87% at 20C after 1000 cyles −1 −1 −1 184 mA·h·g after 100 cycles at 100 mA·g 54% after 1000 cycles at 0.2C 64% after 10,000 cycles at 100C 82.0% after 2000 cycles at 20C [65] [70] [73] [77] [81] [85] [87] [88] [90] [93] [104] [107] [108] [109] Stable at 20 mA·g over 50 cycles Stable over 100 cycles at 0.1C 80% after 300 cycles at 15 mA·g 65% after 300 cycles at 1C 81% after 100 cycles at 0.1C −1

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