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Batteries 2022, 8, 157 20 of 25 References NMBs. Moreover, simply optimizing the solid-state electrolytes in NMBs from a technical level cannot effectively improve the performance of the Na metal anodes. Therefore, further revealing the potential electrochemical mechanisms, including the Na-ion transport behaviors, transfer paths, internal interactions, etc., is also crucial. This understanding will be favorable to guide the design of a new type of solid-state electrolytes with high ionic conductivity and optimization of the configuration and composition of the solid- state electrolytes. Funding: This research is funded by [Shenzhen Science and Technology Program] grant num- ber [JCYJ20200109113606007] and [Science and Technology Program of Guangzhou] grant number [202102020737]. Data Availability Statement: Not applicable. 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