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Ionic substitution shows dramatically improved stability to acidic and alkaline media By making select science-based changes in the NaSICON composition and structure, we have dramatically improved it’s stability to both high and low pH conditions High pH: 10M KOH at 80 oC baseline material fully degraded, and only an amorphous phase with minor ZrO2 secondary phase is present (forms a sludge) The new material retains its structure throughout Low pH baseline material fully degraded, and only an amorphous phase with minor ZrO2 secondary phase is present The new material retains its structure throughtout Baseline NaSICON fully degraded after exposure to 10 M KOH at 80 C. Baseline material NZP (NaZr2P3O12) Crystalline Amorphous (degraded) 10M KOH 80C Ionically substituted NaSICONm-NZP Crystalline Crystalline 10M KOH 80C 5PDF Image | Sodium-Based Battery Development DOE
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