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Chem Soc Rev Review Article Fig. 35 (a) X-ray diffraction patterns on as-synthesized Si nanoparticles and inset image show the morphology of sodiated Si NP electrode after charge/discharge for 100 cycles at 20 mA g1. (b) Cycling test of Si NP electrodes in the voltage range of 0.01–2.8 V. (Reproduced from ref. 475 with permission, Copyright 2015 Wiley- VCH Verlag GmbH & Co. KGaA.) (c) Charge–discharge profiles for selected cycles at 500 mA g1 (inset: the first three CV curves for the nanosized c-Si electrode), (d) in operando Raman analysis of the electrochemical behavior towards Na+ for the nanosized c-Si electrode and (e) schematic illustrations explaining the changes in the nanosized c-Si during cycling. (Reproduced from ref. 476 with permission, Copyright 2016 Wiley-VCH Verlag GmbH & Co. KGaA.) (f) TEM analysis of GeNWs-A-0.1C and GeNWs after initial sodiation process and HAADF micrograph and EELS elemental maps of Ge, Na, Li, and C. (g) Reversible capacity as a function of cycle number for GeNWs and GeNWs-A electrodes. (Reproduced with permission from ref. 481, Copyright 2014 American Chemical Society.) View Article Online 3.3.1.3. Tin. Sn has been regarded as one of the most promising anode materials owing to its high theoretical specific capacity of 847 mA h g1, based on the full sodiation state of Na15Sn4.482–495 Based on the theoretical calculations, Thisjournalis©TheRoyalSocietyofChemistry2017 Chem.Soc.Rev.,2017,46,3529--3614 | 3581 Open Access Article. Published on 28 March 2017. Downloaded on 7/1/2019 3:41:21 AM. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.PDF Image | Sodium-ion batteries present and future
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