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K. Zabielska, T. Aleksandrzak, E. Gabrus ́, Chem. Process Eng., 2018, 39 (3), 309–321 Table 5. Average relative errors δ and coefficients of determination R2 for the carbon dioxide-zeolite 13X system for selected of equilibrium models Equilibrium model Toth Langmuir–Freundlich Langmuir δ, % 8.57 18.79 22.89 R2, – 0.9948 0.9961 0.9657 Fig. 3. Experimental and correlated (Toth equation) isotherms for carbon dioxide adsorption onto zeolite 13X at various temperatures Fig. 4. Experimental and correlated (Toth equation) isotherms for carbon dioxide adsorption onto Zeolite 13X at various temperatures All isotherms are type I according to the IUPAC classification. Type I of adsorption isotherm approaches a limiting value and is used to describe adsorption on microporous adsorbents. At the beginning, adsorption capacity increases in proportion to the pressure and this increase is slowly decreasing, then reaches a constant value. All active sites are occupied and monolayers are created (Keller and Staudt, 2005). 316 http://journals.pan.pl/dlibra/journal/98834PDF Image | ADSORPTION EQUILIBRIUM OF CARBON DIOXIDE ON ZEOLITE
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