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3 Introduction. The experience. The use of the Pressure Swing Adsorption (PSA) process has seen tremendous growth during the last decades mainly due to its simplicity and low operating costs. Major applications have been the recovery of high purity hydrogen, methane and carbon dioxide as well as the generation of nitrogen and oxygen. In addition, it has gained significance for the bulk removal of carbon dioxide from direct reduction top-gases. Linde as the world leader in adsorption technology has designed and supplied more than 500 PSA plants – including the world‘s largest units and units with highest availability. The Linde hydrogen PSA units The well proven Linde high performance PSA units are designed for the recovery and purifi- cation of pure hydrogen from different hydrogen -rich streams, such as synthesis gases from steam reforming process, partial oxidation or gasification, as well as from various off-gases in refineries or petrochemical processes, e.g. ethylene off-gas, coke oven gas, methanol and ammonia purge gas. Capacities range from a few hundred Nm3/h to large scale plants with more than 400,000 Nm3/h. The hydrogen product meets every purity re- quirement up to 99.9999 mol-% and is achieved at highest recovery rates. Main hydrogen consumers are refineries re- quiring this valuable gas for example for their cracking, dearomatization or desulphurization processes. As a second group of users in the petrochemical industry has a demand for hydrogen for its methanol and ammonia synthesis, MTBE pro- cesses, etc. Linde‘s PSA systems have proven to be success- ful in cases where performance, flexibility, avail- ability and reliability are the determining factors. High quality and easy accessibility to all compo- nents minimize and facilitate maintenance to the maximum extent.PDF Image | Hydrogen Recovery by PSA
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