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LIMITS OF SMALL SCALE PRESSURE SWING ADSORPTION

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LIMITS OF SMALL SCALE PRESSURE SWING ADSORPTION ( limits-small-scale-pressure-swing-adsorption )

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Figure 2.1 2.2 2.3 2.4 2.5 2.6 2.7 2.8 3.1 3.2 3.3 3.4 3.5 3.6 4.1 4.2 5.1 5.2 5.3 5.4 LIST OF FIGURES Page Examples of zeolite basic secondary units................................................ 9 Sodalite unit with Si, Al atoms............................................................... 9 Structure of Type A and Type X or Y zeolites.........................,,............... 10 Potential energy diagram for adsorption.................................................. 14 The five types of isotherms................................................................. 15 Depiction of pores and mass transfer resistances in adsorbent particle................ 18 Basic two-column pressure swing adsorption system .................................. 24 Column pressure during Skarstrom cycle ............................................... 25 Calculated potential energy curves of nitrogen and oxygen........................... 34 Potential energy curves of Na+N2 and Li+N2.................................................... 36 Mass transfer zone inside a column................................................................. 45 Shapes of isotherms in determining the sharpness of concentration wavefront.... 46 Self-sharpening wavefront and dispersive wavefront.................................. 46 Column breakthrough curve............................................................... 47 Limiting Peclet number vs particle diameter for flow through packed beds....... 54 Comparison of predicted overall nitrogen MTC using constants and correlations.... according to Table 1................................................................. 58 Oxygen isotherms for LiLSX zeolite........................................................ 68 Nitrogen isotherms for LiLSX zeolite ................................................... 69 Breakthrough experimental setup....................................................... 72 Comparison of experiment and simulation breakthrough curve...................... 77 xiii

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