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Figure 5.4 Comparison of experiment and simulation breakthrough curve at 267 kPa, room temperature and a inlet N2/O2 gas mixture of 0.75/0.25. The average superficial velocity across MTZ was 2.8 cm/s 5.4.5 van Deemter Model While the linear addition approximation is useful for measuring an overall MTC, it is not a good model to estimate relevant mass transfer parameters such as τp and DL using regression analysis. The van Deemter model provides a convenient method for distinguishing between axial dispersion effects and mass transfer resistances due to the particle. Although developed for linear chromatography, the van Deemter expression is often applicable as an engineering approximation for moderately non-linear systems.24, 71 The van Deemter model72 says the height equivalent to a theoretical plate (HETP) for a linear system is expressed as: 77PDF Image | LIMITS OF SMALL SCALE PRESSURE SWING ADSORPTION
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