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LIMITS OF SMALL SCALE PRESSURE SWING ADSORPTION

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LIMITS OF SMALL SCALE PRESSURE SWING ADSORPTION ( limits-small-scale-pressure-swing-adsorption )

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5.6.1 Mass Balance The column component mass balances are represented by the axially dispersed plug flow model introduced in section 3.3.1: The adsorption rate was described with a linear driving force (LDF) model described in section 3.3.1.24 The LDF model simplifies the mass transfer rate to permit faster computation time, which explains its popularity in literature. The LDF approximation should provide reasonable accuracy for the system used. Higher accuracy models exist, but their complexity increases computation time significantly, often without a substantial difference in accuracy.24 The MTC, ki, is typically approximated through literature data or breakthrough experiments by assuming the resistance to macropore diffusion in the adsorbent particle as the limiting resistance.2 5.6.2 Equilibrium Model Adsorption equilibrium was formulated by the dual-site Langmuir (DSL) model. Mathias et al.23 have demonstrated the accuracy of the DSL model for both pure component gases and nitrogen/oxygen mixtures using zeolite 5A. A LiLSX zeolite is similar enough to zeolite 5A to justify using the DSL model to predict mixture 101

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