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approximation for all the experiments. This approximation is not valid in the gas velocity range below our experimental velocities where heat transfer with the environment is more significant. 1 0.8 0.6 0.4 0.2 0 Isothermal Adiabatic Matched experiment 0.8 0.9 1 z/z0 Figure B2. Example of how heat transfer affects experimental results. Matched experiment is run #11. Dashed lines represent 0.95 and 0.9 cutoffs B.4. Model framework The amount adsorbed (nN2) in Equation 5.1 of the main text is found based on the assumption of a constant pattern forming in the column. The constant pattern velocity defined by uw can be expressed as:5 (B1) where M can be molar flux, gas composition, amount adsorbed or temperature. If Ni = ρbni+ɛbCi, Equation 3.11 of the main text can be written as Equation B2 assuming plug flow. A differential mass balance at z and t gives:5 161 C/C0PDF Image | LIMITS OF SMALL SCALE PRESSURE SWING ADSORPTION
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