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PRESSURE SWING ADSORPTION FOR THE PURIFICATION OF HYDROGEN

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PRESSURE SWING ADSORPTION FOR THE PURIFICATION OF HYDROGEN ( pressure-swing-adsorption-forpurification-hydrogen )

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๏‚ท Langmuir: ๐‘ž ๐‘’๐‘ž,๐‘– ๏‚ท = (๐‘ž0 ๐‘’๐‘ž,๐‘– + ๐‘ž1 ๐‘’๐‘ž,๐‘– ๐‘‡) ๐‘๐‘–๐‘๐‘– 1 ๐‘›1+๐‘›2 ๐‘‡ , ๐‘ = ๐‘ ๐‘– 1,๐‘– 1 1 ๐‘’๐‘2,๐‘–(๐‘‡โˆ’๐‘‡๐‘Ÿ๐‘’๐‘“) ๐‘ž0,๐‘–๐‘๐‘–๐‘๐‘–, 1000๐‘2,๐‘–(1โˆ’ 1 ) (3.13) (3.14) ๐‘ž๐‘’๐‘ž,๐‘– =1+โˆ‘๐‘› ๐‘๐‘ ๐‘๐‘– =๐‘1,๐‘–๐‘’ ๐‘—=1 ๐‘— ๐‘— ๐‘‡ ๐‘‡๐‘Ÿ๐‘’๐‘“ Pressure Swing Adsorption for Hydrogen Purification ๏‚ท Langmuir-Freundlich 1+โˆ‘๐‘๐‘1๐‘‡ ๐‘—๐‘—๐‘— 1 ๐‘› +๐‘›2 Ideal Adsorbed Solution (IAS) Theory Temperature dependence of the mass transfer constant in line with Knudsen-type diffusion in pores. Table 3.2 โ€“ Parameters of the existing isotherms in gML libraries Parameter Adsorption constant activation energy Saturation loading Symbol Description ๐‘2 Activation part of the pure-component adsorption equilibrium constant. ๐‘ž0,๐‘1 Pure component Henryโ€™s law constant Adsorption constant pre- exponential factor ๐‘1 Pre-exponential part of the pure- component adsorption equilibrium constant. Inhibition constants ๐›ผ Inhibition constants to describe the effect of each adsorbed component k on the adsorption of a particular component i ๏‚ท Custom model gPROMSยฎ allows the use of a custom isotherm that is written by the user in the custom model isotherm present in gPROMSยฎ libraries. Modelling Tool and Mathematical Model 16

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