PRESSURE SWING ADSORPTION FOR THE PURIFICATION OF HYDROGEN

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PRESSURE SWING ADSORPTION FOR THE PURIFICATION OF HYDROGEN ( pressure-swing-adsorption-forpurification-hydrogen )

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Table 5.18 - Final values obtained for the parameter estimation of the Multisite Langmuir isotherm in the zeolite layer Pressure Swing Adsorption for Hydrogen Purification Component H2 Parameter 𝑎 Value from literature Initial value Final value Confidence interval 95% 90% 99% 879.5 Zeolite 1.0 1 1.67 560.9 668.7 0.094 𝑞𝑚𝑎𝑥 9.954 10 - - - - 𝐾∞ 50.76 × 10−6 5×10−5 2.24 × 10−4 0.060 0.071 𝑎 CH4 𝐾∞ 2.0 2 1.31 1178 1404 1847 0.1131 9239 75.01 0.00067 136.9 260.8 0.0016 822.5 870.1 0.042 1760 35.65 × 10−6 𝑞𝑚𝑎𝑥 4.976 4×10−6 4.1 × 10−6 5 6.84 2 1.67 1×10−5 9.7 × 10−6 4.5 4.56 3 1.40 4×10−6 4.44 × 10−6 0.072 5892 47.84 0.00043 87.3 166.3 0.001 0.086 7024 57.03 0.00051 104.1 198.2 0.0012 CO2 CO N2 𝑎 2.2 𝐾∞ 11.11 × 10−6 𝑞𝑚𝑎𝑥 4.525 𝑎 2.6 𝐾∞ 3.937 × 10−6 𝑞𝑚𝑎𝑥 3.828 𝑎 2.4 𝐾∞ 30.83 × 10−6 4 4.9 524.5 625.3 2.5 1.85 555 661.5 3×10−5 4.75 × 10−5 0.027 0.032 𝑞𝑚𝑎𝑥 4.148 4 4.14 1123 1338 Parameter Estimation 74

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