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accessible SII* supercage position. The presence of this supercage cation (at the SII* site) results in an adsorptive surface which is energetic heterogeneous. Literature Cited Bajusz, I. G., and J. G. Goodwin, “N2 Adsorption in LiX Zeolite: Isotopic Transient Analysis”, Langmuir, 13, 6550 (1997). Barrer, R. M.; Zeolites and Clay Minerals as Sorbents and Molecular Sieves, Academic Press: London, 1978. Breck, D. W.; Zeolite Molecular Sieves, R. E. Krieger Publishing: Malabar, FL, 1984. Chao, C. C., “Process for Separating Nitrogen from Mixtures Thereof with Less Polar Substances”, US Patent 4,859,217 (1989). Chao, C. C., J. D. Sherman, J. T. Mullhaupt, and C. M. Bolinger, “Mixed Ion-exhanged Zeolites and Processes for the Use Thereof in Gas Separations”, U. S. Patent 5,174,979 (1992). Chen, N., and R. T. Yang, “An ab Initio Molecular Orbital Study of Adsorption of Oxygen, Nitrogen and Ethylene on Silver-Zeolite and Silver Halides”, Ind. Eng. Chem. Res., 35, 4020 (1996). Coe, C. G., J. F. Kirner, R. Pierantozzi, and T. R. White, “Nitrogen Adsorption with a Ca and/or Sr Exchanged Zeolite”, U. S. Patent 5,152,813 (1992). Coe, C. G., in Access in Nanoporous Materials, T. J. Pinnavaia and M. F. Thorpe (Eds.), Plenum Press, New York, 1995 (p. 213). Feuerstein, M., and R. F. Lobo, “Characterization of Li Cations in Zeolite LiX by Solid- State NMR Spectroscopy and Neutron Diffraction”, Chem. Mater., 10, 2197 (1998). Finger, L. W., D. E. Cox, and A. P. Jephcoat, "Correction for Powder Diffraction Peak Asymmetry Due to Axial Divergence", J. Appl. Crystallogr., 27, 892 (1994). Fitch, F. R., M. Bulow, and A. F. Ojo, “Adsorptive Separation of Nitrogen and Other Gases”, U. S. Patent 5,464,467 (1995). Freeman, C. M., C. R. A. Catlow, J. M. Thomas, and S. Brode, “Computing the Location and Energetics of Organic Molecules in Microporous Adsorbents and Catalysts: a Hybrid Approach Applied to Isomeric Butenes in a Model Zeolite,” Chem. Phys. Lett., 186, 137 (1991). 103PDF Image | PSA USING SUPERIOR ADSORBENTS
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