PSA USING SUPERIOR ADSORBENTS

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PSA USING SUPERIOR ADSORBENTS ( psa-using-superior-adsorbents )

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Figure Captions Figure 1. The molecular structure for Co(salen) [for X=H] and Co(fluomine) [for X=F]. Figure 2. Oxygen adsorption and desorption isotherms, measured at 25 C for Co(salen). Figure 3. Oxygen adsorption and desorption isotherms, measured at 25 C for Co(fluomine). Figure 4. Oxygen adsorption and desorption isotherms, measured at 0 60 C for Co(fluomine). Figure 5. Oxygen and nitrogen adsorption isotherms, measured at 25 and Co(fluomine) on LSX zeolite. Figure 6. Oxygen adsorption and desorption isotherms, measured at 0 60 C for Co(fluomine) on Low Silica X zeolite. Figure 7. Oxygen and nitrogen adsorption isotherms, measured at 25 CoFluomine-MCM-41. Figure 8. Oxygen and nitrogen adsorption isotherms, measured at 25 Co(fluomine) on Ion Exchange Resin Amberlyst-15. C, 25 C, and C, for Co-LSX C, 25 C and C, for C, for Figure 9. Types of Metal-dioxygen geometries.30 Figure 10. X-ray photoemission spectra (XPS) for various cobalt species. Figure 11. Stability curves for various O2-binding materials after oxygenation and dexoygenation cycling. The materials were each cycled for 15 minutes each in 1 atmosphere O2 and Ar at 60 C. The materials are Co(fluomine), Co(fluomine)-LSX synthesized with the use of piperidine (p), Co(fluomine)-LSX synthesized without the use of piperidine (np), and Co(fluomine)-MCM-41. 177

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