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Structured Zeolite Adsorbents for PSA Applications

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Structured Zeolite Adsorbents for PSA Applications ( structured-zeolite-adsorbents-psa-applications )

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Table 1 Sample code C5400 C5900 NaX beads Synthesis conditions Clear solution, 100o C, 5 steps of 1 h 20 min Clear solution, 100o C, 5 steps of 1 h 20 min n.a. Film thickness ( m) 1.5 1.7 n.a. Weight gain (g/gsample) Surface area (m2/gsample) Zeolite Mesop. loading a volb (gzeolite/gsample) (cm3/gzeolite) a from BET b from BJH method Table 2 Structure CO2 C5400 C5900 NaX beads N2 C5400 C5900 NaX beads Table 3 CO2 (0° C) CO2 (20° C) CO2 (40° C) N2 (0° C) N2 (20° C) N2 (40° C) m1 (mol/kg) 0.0894 0.1274 2.5495 0.0523 0.0099 0.004 0.036 0.054 n.a. m2 (mol/kg) 0.0966 0.1546 2.4139 0 0.3544 2.6785 18.02 0.025 31.00 0.043 437 0.83 b0 (1/kPa) Q1 (J/mol) 2.86E-07 35240.79 3.98E-08 40526.02 7.40E-07 32896.5 3.09E-07 17644.1 2.42E-05 14391.35 5.50E-13 59282.86 0.08 0.06 0.12 d0 (1/kPa) 1.22E-07 1.48E-07 3.99E-08 0.00E+00 2.69E-08 1.26E-06 Q2 (J/mol) 29676.35 29512.72 32998.2 0 21785.65 15962.24 Adsorption capacity, mmol/cm3 C5400 C5900 0.053 0.082 0.041 0.072 0.035 0.061 0.003 0.006 0.002 0.004 0.001 0.002 NaX beads 2.334 2.001 1.477 0.181 0.114 0.071 133

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