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would fail when preferential location at the intersections of framework are present,105 as it is the case of zeolite 13X and Mg-MOF-74, two highly selective materials for CO2-over- N2. Besides, there are many factors in mixtures able to alter the expected results from IAST due to interactions of new particles competing to be adsorbed, and which may provoke inhibition problems or, contrarily, to enhance adsorption, as it happens with some gases. This is one of the advantages of using GCMC simulations, as they allow calculating interactions between molecules in a direct manner, where competitions for adsorption are explicitly included, as will be discussed in the next sections. 22PDF Image | swing adsorption processes for CO2 capture in selected MOFs and zeolites
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