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Six operating conditions are shown (two for each process), corresponding to 10bar→1bar and 20bar→1bar for PSA, 1bar→0.1bar and 1bar→0.05bar for VSA, while the TSA operating conditions under study were 383K→313K and 443K→313K. Constant condition of 313K was set for VSA and PSA, and pressure at 1bar for TSA. For VSA conditions, zeolite 13X shows higher working capacities than CuBTC and Mg-MOF-74, especially when the pressure at the desorption step is lowered to 0.05 bar. However, when it comes to water traces in the mixture, MOFs structures show better performance. CO2 working capacities decline after water sorption in almost all cases, being more noticeable in the zeolite, as already explained for the adsorption capacity. 29PDF Image | swing adsorption processes for CO2 capture in selected MOFs and zeolites
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