TEMPERATURE SWING ADSORPTION PROCESSES FOR GAS SEPARATION

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TEMPERATURE SWING ADSORPTION PROCESSES FOR GAS SEPARATION ( temperature-swing-adsorption-processes-for-gas-separation )

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LIST OF TABLES Table 2.1. Simulation parameters and material properties (Mark, 1999; Lee, 2007; Determan et al., 2011)..................................................................................24 Table 2.2. Purification cycle simulation criteria and monitored variables. ......................39 Table 2.3. Boundary Conditions for the microchannel species and energy equations. .....40 Table 2.4. Coefficients for the Langmuir equations with competitive adsorption (Babarao et al., 2007; Lee, 2007).................................................................................42 Table 2.5. Effect of microchannel diameter on adsorption stage performance ................46 Table 2.6.Effect of adsorbent layer thickness on adsorption stage performance ..............49 Table 2.7. Comparison of properties of water and PAO (Process Systems Enterprise, 1997-2015; Chevron, 2008)..........................................................................52 Table 2.8. Comparison of stage times with silicalite-water and zeolite 5A – PAO for a temperature swing of 75°C ...........................................................................53 Table 2.9. Final stage times and total cycle time selected for the full process simulation57 Table 2.10. Single-point process performance comparison with the literature ................65 Table 3.1. Stage times and total cycle time selected for the full process simulation ........69 Table 3.2. Effect of reduction in ΔP on purification cycle time. .....................................85 Table 3.3. Effect of reduction in ΔP on energy required for process components ...........86 Table 3.4. Heat recovery during cooling stage. ..............................................................88 Table 4.1. Calculated uncertainties for sensors.............................................................114 Table 4.2. Numerical values of parameters used for simulation....................................118 Table 4.3. Auxiliary parameters for competitive DSL equation used for estimation of zeolite 5A adsorbent capacity and intra-crystalline diffusion coefficient (Gholami and Talaie, 2009)........................................................................122 ix

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