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LIST OF FIGURES Figure 1.1. Fractions of non-renewable fuels as USA primary energy (EIA, 2015)..........2 Figure 1.2. Globally increasing natural gas consumption (Schaal, 2013). .........................2 Figure 1.3. Sequential purification of natural gas (Brooks, 2013) .....................................3 Figure 1.4. Prudhoe bay natural gas processing plant in Alaska (White, 2014) .................4 Figure 1.5. Adsorbent bed design with alternate rows of adsorbent-coated and HTF microchannels (Pahinkar et al., 2016). ..........................................................7 Figure 2.1. Improvements in selectivity of mixed matrix membranes by increasing adsorbent loading in polymers (Koros and Mahajan, 2000; Bernardo et al., 2009). .........................................................................................................15 Figure 2.2. CO2 adsorption isotherms for MOFs, activated carbon zeolites and silicalite at 25°C (Lee, 2007; Gholami and Talaie, 2009; Shao et al., 2011; Herm et al., 2012; Xiang et al., 2012) ............................................................................17 Figure 2.3. Schematics of the stages in the proposed TSA based purification cycle. Red dots indicate adsorbent crystals in the gray hollow binder matrix and small yellow dots indicate CO2 impurity in pure CH4 shown as yellow background. ...................................................................................................................21 Figure 2.4. Computational modeling architecture of the purification process.................22 Figure 2.5. Illustration of (a) Initial convective diffusive flow and (b) subsequent slow diffusive flow .............................................................................................33 Figure 2.6. (a) Schematic representation of water evaporation as it is exposed to concentration gradient (b) Illustration of an instant in time during water removal.......................................................................................................35 xiPDF Image | TEMPERATURE SWING ADSORPTION PROCESSES FOR GAS SEPARATION
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