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TEMPERATURE SWING ADSORPTION PROCESSES FOR GAS SEPARATION

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TEMPERATURE SWING ADSORPTION PROCESSES FOR GAS SEPARATION ( temperature-swing-adsorption-processes-for-gas-separation )

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The modeling architecture considered for the process is shown in Figure 3.1, which also shows purge gas recirculation and HTF recirculation paths. The HTF is recirculated to avoid the need of a fresh batch of HTF to be sent through the monolith for each cycle. This requires an investigation of the effect of liquid absorption on cyclic steady state of the process and its influence on product collection. The governing equations used for modeling the absorption of gas in the HTF are based on condensability of gases in the presence of a pressurized liquid. As gases are pressurized at the system temperature, the mass of gases that changes phase and mixes with the liquid HTF can be calculated by using Equations (3.1) and (3.2) (Reid et al., 1986). (3.1) (3.2) The saturation pressures of CH4 and CO2 in Equation (3.1) as a function of temperature can be calculated using Equations (3.3) and (3.4), respectively (Reid et al., 1986). These curves are fitted based on the variation of the saturation pressure of each of the component gases with temperature (Klein, 2016). The dissolved species are considered to be in equilibrium with the liquid. xi,abs  xi,G  Cg,i,abs  yi,G,abs  L g PeT  (3.3) (3.4) CH4 ,G,sat P sys P i,G,sat  1023.41   13.78   2012.41   15.522  g PeT  CO2,G,sat 70

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TEMPERATURE SWING ADSORPTION PROCESSES FOR GAS SEPARATION

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