TEMPERATURE SWING ADSORPTION PROCESSES FOR GAS SEPARATION

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TEMPERATURE SWING ADSORPTION PROCESSES FOR GAS SEPARATION ( temperature-swing-adsorption-processes-for-gas-separation )

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Figure 4.2. (a) Heat transfer (b) mass transfer results from the adsorption experiments on PLOT column (ΔP = 18 kPa, L = 2 m) Figure 4.2(b) also shows that trace amount of water vapor is present at the microchannel outlet, which complicates the repeatability analysis. Although present in trace quantities, it suppresses CO2 adsorption and shows a resistance to desorption in presence of a pure He purge. It is known that zeolite 5A has a greater affinity and adsorption capacity for water than for CO2 (Gholami and Talaie, 2009); therefore, in a competitive adsorption situation of water and CO2, water precludes any CO2 adsorption and is the dominant adsorbate. The trace water is not able to generate an adsorption 109

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